type: misc

label: url

en: レーダー 無機層状化合物の剥離ナノシートの複合体と機能

ja: レーダー 無機層状化合物の剥離ナノシートの複合体と機能

en: Chemistry and Education

ja: 化学と教育


en: 注目の論文 100倍に膨らむ無機層状物質 --- 瞬く間に膨らんで，またもとどおり

en: 化学

ja: 化学


en: 化学応用工学科のFD活動について

ja: 化学応用工学科のFD活動について

en: 平成23年度FD研究報告書

ja: 平成23年度FD研究報告書

misc_type: others


en: Synthesis of Poly(biphenylene ruthenacyclopentatrienylene), a New Organometallic Conducting Polymer with Ferromagnetic Interaction in Its Reduced State

en: A ruthenacyclopentatriene polymer 2 was synthesized by metallacycling polymerization (MCP). Polymer 2 with Mn = 3400 and Mw = 5800 consisted of identical ruthenacyclopentatriene units. The UV-vis spectra of 2 showed a shift of the pi-pi* band to a longer wavelength due to the enlargement of the pi-conjugation. Polymer 2 underwent reversible reduction due to the ruthenacycle moiety at -1.01 V versus ferrocenium/ferrocene. The EPR spectrum of the reduced form of 2 in frozen THF indicated ferromagnetic interaction of spins at ruthenacyclopentatriene units.

en: Journal of the American Chemical Society