Tokushima University / Educator and Researcher Directory --- Miyoshi, Norikazu

Personal Web Page

https://researchmap.jp/read0184071 (researchmap)

Field of Study

○	Organic Chemistry

Subject of Study

○	The deveropement of new synthetic methodology, Investigation of new synthetic chemistry (methodology, organic chemistry, new synthesis) (I am researching the deveropement of new convinient and high-selective synthetic methods using not expensive and not toxic ragents and catalysts. And I am also invesitaging new synthetic chemistry.)

Book / Paper

Book:

1.	Norikazu Miyoshi : Science of Synthesis; Houben-Weyl 7, --- Product Class 8; Strontium Compounds ---, Georg Thieme Verlag, Stuttgart (Germany), Jul. 2004.

Academic Paper (Judged Full Paper):

1.	Miho Kobatake, Norikazu Miyoshi and Masaharu Ueno : One-pot Tandem Coupling Method for the Short Step Formal Synthesis of Riccardin C, Chemistry - A European Journal, Vol.29, e202203805, 2023. (Summary) One-pot reactions reduce reagent amounts and circumvent process treatments, such as work-up and purifications in multi-step reactions. In this study, we achieved the formal total synthesis of riccardin C through a one-pot reaction by simultaneously linking four units through two Sonogashira coupling reactions and one Suzuki coupling reaction, followed by reduction and deprotection. Thus, this one-pot method comprised five steps and did not require the purification of intermediate reaction mixtures, which saves resources, such as reagents and solvents, and expedites the work process. (Tokushima University Institutional Repository) ● Metadata: 117971 (Link to Publication Site) ● Publication site (DOI): 10.1002/chem.202203805 (Link to Search Site for Scientific Articles) ● PubMed @ National Institutes of Health, US National Library of Medicine (PMID): 36573022 ● Search Scopus @ Elsevier (PMID): 36573022 ● Search Scopus @ Elsevier (DOI): 10.1002/chem.202203805 (Tokushima University Institutional Repository: 117971, DOI: 10.1002/chem.202203805, PubMed: 36573022)
2.	Norikazu Miyoshi, Aki Miyoshi, Yasuaki Miyazaki, Shigeki Kubo and Masaharu Ueno : Practical Method for Hydroxyl-Group Protection Using Strontium Metal and Readily Available Silyl Chlorides, Chemical Communications, Vol.58, No.43, 6312-6315, 2022. (Summary) We have found that the etherification of silyl-protected secondary alcohols proceeds smoothly in the presence of strontium metal using silyl chloride instead of the expensive, yet more reactive, and commonly used silyl triflate. The reaction occurred almost completely with various alcohols. (Keyword) Alcohols / Chlorides / Strontium (Tokushima University Institutional Repository) ● Metadata: 117879 (Link to Publication Site) ● Publication site (DOI): 10.1039/d2cc01105k (Link to Search Site for Scientific Articles) ● PubMed @ National Institutes of Health, US National Library of Medicine (PMID): 35522074 ● Search Scopus @ Elsevier (PMID): 35522074 ● Search Scopus @ Elsevier (DOI): 10.1039/d2cc01105k (Tokushima University Institutional Repository: 117879, DOI: 10.1039/d2cc01105k, PubMed: 35522074)
3.	Norikazu Miyoshi, Shohdai Kimura, Shigeki Kubo, Satoshi D. Ohmura and Masaharu Ueno : Chemoselective Ketone Synthesis by the Strontium-mediated Alkylation or Arylation of N,N-Dimethylamides or Urea, Asian Journal of Organic Chemistry, Vol.9, No.10, 1660-1664, 2020. (Tokushima University Institutional Repository) ● Metadata: 116160 (Link to Publication Site) ● Publication site (DOI): 10.1002/ajoc.202000389 (Link to Search Site for Scientific Articles) ● Search Scopus @ Elsevier (DOI): 10.1002/ajoc.202000389 (Tokushima University Institutional Repository: 116160, DOI: 10.1002/ajoc.202000389)
4.	Masaharu Ueno, Norikazu Miyoshi, Hanada Kentaro and Kobayashi Shu : Three-component, one-pot tandem Sonogashira/Suzuki-Miyaura coupling reactions for the synthesis of a library of ceramide-transport protein inhibitors that were designed in silico, Asian Journal of Organic Chemistry, Vol.9, No.2, 267-273, 2020. (Summary) We have developed a onepot, tandem Sonogashira/SuzukiMiyaura coupling reaction, which is unknown synthetically, and applied it for the synthesis of a library of potential natural ligand nonmimetic inhibitors of the lipidtransfer protein, ceramidetransport protein (CERT). The characteristic feature of this reaction is that the twostep coupling reaction proceeds smoothly with only 5 mol% of palladium catalyst. Furthermore, the location of the formed carboncarbon bond would be strictly defined because of the difference in reactivity. Therefore, many derivatives could be synthesized in high yields without the formation of regioisomeric byproducts by the same procedure. We also performed a semigram scale synthesis of several derivatives to provide the bioactive assey. After synthesizing as many as 113 derivatives, we identified a nonnatural mimetic inhibitor with activity comparable to that of the known inhibitor (1R,3S)-HPA-12. (Tokushima University Institutional Repository) ● Metadata: 115072 (Link to Publication Site) ● Publication site (DOI): 10.1002/ajoc.201900689 (Link to Search Site for Scientific Articles) ● Search Scopus @ Elsevier (DOI): 10.1002/ajoc.201900689 (Tokushima University Institutional Repository: 115072, DOI: 10.1002/ajoc.201900689)
5.	Satoshi D. Ohmura, Toshikazu Hirao, Norikazu Miyoshi and Toshiyuki Moriuchi : Cocrystal Structure of the Redox-active Phenylenediamine and Quinonediimine Derivatives, X-ray Structure Analysis Online, Vol.35, No.11, 63-65, 2019. (Tokushima University Institutional Repository) ● Metadata: 113986 (Link to Publication Site) ● Publication site (DOI): 10.2116/xraystruct.35.63 (Link to Search Site for Scientific Articles) ● Summary page in Scopus @ Elsevier: 2-s2.0-85077626610 (Tokushima University Institutional Repository: 113986, DOI: 10.2116/xraystruct.35.63, Elsevier: Scopus)
6.	Satoshi D. Ohmura, Keisuke Yamana, Masaharu Ueno and Norikazu Miyoshi : Methoxycarbonyl Group as a Conformational Regulator for the Benzene Ring of Triphenylamines, ChemistrySelect, Vol.4, No.13, 3799-3802, 2019. (Keyword) triphenylamine / luminescence / substitutional effect / methoxycarbonyl group (Tokushima University Institutional Repository) ● Metadata: 113987 (Link to Publication Site) ● Publication site (DOI): 10.1002/slct.201900076 (Link to Search Site for Scientific Articles) ● Search Scopus @ Elsevier (DOI): 10.1002/slct.201900076 (Tokushima University Institutional Repository: 113987, DOI: 10.1002/slct.201900076)
7.	Masaharu Ueno, Satoshi D. Ohmura, Makoto Wada and Norikazu Miyoshi : Aerobic oxidation of alcohols using bismuth bromide as a catalyst, Tetrahedron Letters, Vol.60, No.7, 570-573, 2019. (Summary) We developed an environmentally friendly method for aerobic oxidation of alcohols using a commercially available, relatively benign bismuth salt as a catalyst. We found that the catalytic combination of BiBr3 with nitric acid is key for enhancing the reactivity. The reaction proceeds well under air, making the use of pure oxygen unnecessary. Each of the primary or secondary alcohols tested was oxidized to the corresponding aldehydes or ketones using this protocol. (Tokushima University Institutional Repository) ● Metadata: 112992 (Link to Publication Site) ● Publication site (DOI): 10.1016/j.tetlet.2019.01.034 (Link to Search Site for Scientific Articles) ● Search Scopus @ Elsevier (DOI): 10.1016/j.tetlet.2019.01.034 (Tokushima University Institutional Repository: 112992, DOI: 10.1016/j.tetlet.2019.01.034)
8.	Masaharu Ueno, Kusaka Ryo, Satoshi D. Ohmura and Norikazu Miyoshi : Environmentally Benign Ritter Reaction Using Bismuth Salt as a Catalyst, European Journal of Organic Chemistry, Vol.2019, No.8, 1796-1800, 2019. (Summary) We developed the environmentally benign Ritter reaction using commercially available, less harmful bismuth salt as a catalyst. The reaction proceeded smoothly even using stoichiometric amount of nitrile to alcohol without any solvents. We also succeeded in establishing a purification process without using any organic solvents. (Tokushima University Institutional Repository) ● Metadata: 113060 (Link to Publication Site) ● Publication site (DOI): 10.1002/ejoc.201801882 (Link to Search Site for Scientific Articles) ● Search Scopus @ Elsevier (DOI): 10.1002/ejoc.201801882 (Tokushima University Institutional Repository: 113060, DOI: 10.1002/ejoc.201801882)
9.	Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : Strontium-mediated selective protonation of unsaturated linkage of aromatic hydrocarbons and these derivatives, Tetrahedron Letters, Vol.59, No.23, 2268-2271, 2018. (Keyword) Birch-like reduction / Strontium metal / Selective protonation / Aromatic hydrocarbons / Unsaturated linkage (Tokushima University Institutional Repository) ● Metadata: 113988 (Link to Publication Site) ● Publication site (DOI): 10.1016/j.tetlet.2018.04.074 (Link to Search Site for Scientific Articles) ● Search Scopus @ Elsevier (DOI): 10.1016/j.tetlet.2018.04.074 (Tokushima University Institutional Repository: 113988, DOI: 10.1016/j.tetlet.2018.04.074)
10.	Keisuke Oyama, Norikazu Miyoshi and Yasuo Oyama : Cytometric analysis on cytotoxicity of 4,4 -methylenediphenyl diisocyanate, a chemical allergen, in rat thymocytes, Fundamental Toxicological Sciences, Vol.4, No.4, 173-178, 2017. (Summary) 4,4'-Methylenediphenyl diisocyanate (MDI) is a cross-linking agent. Chemical reactivity of MDI with endogenous substances such as albumin and glutathione (GSH) is assumed to be responsible for MDI toxicity. We examined the cytotoxic effect of MDI on rat thymocytes, under the condition that endogenous biological substances except for cells were nominally absent, in order to study chemico-biological interactions between MDI and cells. The treatment of 10 50 µM MDI for 3 h significantly increased the side scatter signal intensity of cytograms, without affecting forward scatter intensity. The increase in side scatter signal intensity by MDI was associated with an increase in cell lethality. The treatment of cells with 50 µM MDI for 3 h increased cell lethality without increasing the population of pre-apoptotic annexin V-positive living cells. In contrast, H2O2 at 100 µM significantly increased the population of annexin V positive living cells prior to cell death. MDI at 30 50 µM did not affect the increase in cell lethality induced by H2O2 or A23187. Simultaneous application of 50 µM GSH did not affect the cytotoxicity of 50 µM MDI. It was therefore concluded that the process of cell death induced by MDI could not be attributed to oxidative stress and intracellular Ca2+ overload, and that MDI possesses cytotoxic actions that are not significantly related to its chemical reactivity with GSH. (Tokushima University Institutional Repository) ● Metadata: 111202 (Link to Publication Site) ● Publication site (DOI): 10.2131/fts.4.173 (Link to Search Site for Scientific Articles) ● Search Scopus @ Elsevier (DOI): 10.2131/fts.4.173 (Tokushima University Institutional Repository: 111202, DOI: 10.2131/fts.4.173)
11.	Satoshi D. Ohmura, Yasuaki Miyazaki, Daisuke Kanehiro, Yuka Yamaguchi, Saki Kitakata, Sawa Tateda, Takahiro Nishizawa, Ryosuke Shimoda, Gen Nagaoka, Masaharu Ueno and Norikazu Miyoshi : Superior Alkylating Agents for Bulky Esters/Ketones via Strontium-Mediated Barbier-Type Reaction, Asian Journal of Organic Chemistry, Vol.6, No.7, 821-824, 2017. (Keyword) adamantanone / alkylation / Barbier-type reaction / ester / strontium (Link to Publication Site) ● Publication site (DOI): 10.1002/ajoc.201700209 (Link to Search Site for Scientific Articles) ● Summary page in Scopus @ Elsevier: 2-s2.0-85020473609 (DOI: 10.1002/ajoc.201700209, Elsevier: Scopus)
12.	Satoshi D. Ohmura, Choki MUROI, Hajime SAKATA, Makoto Wada and Norikazu Miyoshi : Depolymerization of Waste PET with Phosphoric Acid-Modified Silica Gel Under Microwave Irradiation, Journal of Polymers and the Environment, Vol.25, No.2, 250-257, 2016. (Keyword) Poly(ethylene terephthalate) / Depolymerization / Solid catalyst / Microwave (Link to Publication Site) ● Publication site (DOI): 10.1007/s10924-016-0802-7 (Link to Search Site for Scientific Articles) ● Search Scopus @ Elsevier (DOI): 10.1007/s10924-016-0802-7 (DOI: 10.1007/s10924-016-0802-7)
13.	Yusuke Takahashi, Kaori Kanemaru, Shoji Imai, Norikazu Miyoshi, Takuya Kawanai and Yasuo Oyama : Yttrium decreases the intracellular Zn²⁺ concentration in rat thymocytes by attenuating a temperature-sensitive Zn²⁺ influx, Environmental Toxicology and Pharmacology, Vol.34, No.2, 574-578, 2012. (Summary) Yttrium is used in the production of various electronic devices because the alloy it contains enhances or modifies the properties of other elements. In order to study the cytotoxic action of yttrium, the effect of yttrium chloride (YCl3) on the intracellular Zn2+ level was examined in rat thymocytes using a flow cytometer with FluoZin-3-AM and propidium iodide. The application of YCl3 significantly decreased the intensity of the FluoZin-3 fluorescence, suggesting a decrease in the intracellular Zn2+ level or quenching of the FluoZin-3 fluorescence by Y3+. However, since Y3+ did not attenuate the FluoZin-3 fluorescence under cell-free conditions, the latter suggestion was ruled out. Rat thymocytes possess a temperature-sensitive membrane pathway that carries Zn2+ into the cells. The application of YCl3 attenuated the FluoZin-3 fluorescence augmented by externally applied ZnCl2 in a concentration-dependent manner. This suggested that Y3+ inhibited the Zn2+ influx, resulting in the decrease in the intracellular Zn2+ level. Yttrium may induce dyshomeostasis of intracellular Zn2+, leading to some cytotoxic actions. (Link to Publication Site) ● Publication site (DOI): 10.1016/j.etap.2012.07.002 (Link to Search Site for Scientific Articles) ● PubMed @ National Institutes of Health, US National Library of Medicine (PMID): 22854244 ● Summary page in Scopus @ Elsevier: 2-s2.0-84864332430 (DOI: 10.1016/j.etap.2012.07.002, PubMed: 22854244, Elsevier: Scopus)
14.	Takuya Kawanai, Masahiro Fujinaga, Kazuki Koizumi, Isao Kurotani, Erika Hashimoto, Masaya Satoh, Shoji Imai, Norikazu Miyoshi and Yasuo Oyama : Some characteristics of membrane Cd²⁺ transport in rat thymocytes: An analysis using Fluo-3, Biometals, Vol.24, No.5, 903-914, 2011. (Summary) Although cadmium-induced apoptosis of lymphocytes is one of common features in the immunotoxicity of cadmium, the membrane pathway for intracellular cadmium accumulation is not fully elucidated. To characterize membrane Cd2+ transport of rat thymocytes, the change in intracellular Cd2+ concentration under various conditions was examined by the use of Fluo-3, a fluorescent probe for monitoring the change in intracellular concentration of divalent metal cations. The membrane Cd2+ transport was estimated by the augmentation of Fluo-3 fluorescence induced by bath application of CdCl2. Lowering temperature strongly suppressed the augmentation of Fluo-3 fluorescence by CdCl2, suggesting that the metabolic process can be involved in membrane Cd2+ transport. External acidification (decreasing pH) and membrane depolarization by adding KCl attenuated the augmentation, indicating the requirement of electrochemical driving force for membrane Cd2+ transport into the cells. Bath application of CaCl2 and ZnCl2 equally decreased the augmentation, suggesting their competition with Cd2+ at the membrane transport. The augmentation by CdCl2 was lesser in the cells treated with N-ethylmaleimide inducing chemical depletion of cellular thiols. The result suggests the contribution of sulfhydryl groups to membrane Cd2+ transport. Taken together, it is suggested that the cells possess a temperature-sensitive membrane Cd2+ pathway, driven by electrochemical gradient of Cd2+ and transmembrane potential, with competitive binding site. Based on the characteristics described above, it is unlikely that the membrane Cd2+ transport in rat thymocytes is attributed to a single transport system although it has characteristics that are similar to those of divalent cation transporter 1. (Keyword) Environmental pollutants (Link to Publication Site) ● Publication site (DOI): 10.1007/s10534-011-9444-3 (Link to Search Site for Scientific Articles) ● PubMed @ National Institutes of Health, US National Library of Medicine (PMID): 21455662 ● Summary page in Scopus @ Elsevier: 2-s2.0-80052401060 (DOI: 10.1007/s10534-011-9444-3, PubMed: 21455662, Elsevier: Scopus)
15.	Takashi Yamamoto, Makoto Kikuchi, Saki Okada, Kazuhide Yamashita, 佐田知沙, Shoji Imai, Norikazu Miyoshi and Makoto Wada : スチレン類二量化に有効な鉄シリカ触媒のXAFS法による構造解析, Advances in X-Ray Chemical Analysis, Japan, Vol.42, 237-248, 2011. (Summary) α-メチルスチレン二量化反応に活性を示す鉄ゾル-ゲル法にて調製した鉄シリカ触媒をX線回折およびX線吸収分光法により評価した．触媒中鉄種の存在状態は仕込みSi /Fe 比に依存し，100 以上では四面体FeOxCl4-x種，50以下ではα-Fe2O3 凝集種が主成分であり，その存在比をXANES解析により求めた．シリカマトリクスに捕捉された孤立FeOxCl4-x が活性種として機能し，固体酸性質を発現する機構について論じた． (Keyword) Iron ion / Silica / Solid acid catalyst / XAFS / α-methylstyrenedimerization (Tokushima University Institutional Repository) ● Metadata: 111220 (Link to Publication Site) ● Publication site (DOI): 10.57415/xshinpo.42.0_237 (Link to Search Site for Scientific Articles) ● CiNii @ National Institute of Informatics (CRID): 1050282812443012224 ● Search Scopus @ Elsevier (DOI): 10.57415/xshinpo.42.0_237 (Tokushima University Institutional Repository: 111220, DOI: 10.57415/xshinpo.42.0_237, CiNii: 1050282812443012224)
16.	Norikazu Miyoshi, Makoto Kikuchi and Makoto Wada : The Development of the New Synthetic Methods Using Metallic Strontium, Journal of Synthetic Organic Chemistry, Japan, Vol.67, No.12, 1274-1281, 2009. (Summary) We found the interesting results that alkylation of carboxylic acids with methyl iodide using strontium metal proceeded smoothly to afford the corresponding monomethylated ketones, rather than the dimethylated alcohols, preferentially in moderate to good yields. Using the carboxylic acid sodium salt, the yield decreases slightly, but the reaction controls the over-addition of methyla-ting agent to give the dramatically improvement with high selectivities. Next, when benzoic acid reacted with metallic strontium and alkyl iodides, the unexpected reactions occurred to give <I>p</I>-alkylated products of the aromatic ring of benzoic acid in a trace amount. We were interested in the <I>p</I>-allylated product because this allylation reaction is unusual in these conditions and there are only a few reports of the <I>p</I>-alkylation of aromatic carbonyl compounds. As the results of various investigations, the <I>p</I>-alkylated products were obtained predominantly in good yields. Furthermore, it was found that the convenient bulky <I>tert</I>-benzylic alcohol benzoates were prepared by the dialkylation of methyl benzoate with methyl or <I>i</I>-butyl iodide in the presence of metallic strontium, followed by the addition of benzoyl chloride, benzoic anhydride or acetic anhydride as two portions. (Keyword) organic chemistry (Link to Publication Site) ● Publication site (DOI): 10.5059/yukigoseikyokaishi.67.1274 (Link to Search Site for Scientific Articles) ● CiNii @ National Institute of Informatics (CRID): 1390001205312512256 ● Search Scopus @ Elsevier (DOI): 10.5059/yukigoseikyokaishi.67.1274 (DOI: 10.5059/yukigoseikyokaishi.67.1274, CiNii: 1390001205312512256)
17.	Hisao Nemoto, Tomoyuki Kawamura and Norikazu Miyoshi : A Highly Efficient Carbon-Carbon Bond Formation Reaction via Nucleophilic Addition to N-Alkylaldimines without Acids or Metallic Species, Journal of the American Chemical Society, Vol.127, No.42, 14546-14547, 2005. (Summary) A nucleophilic addition reaction to N-methylaldimines without acid or metal species is described. A novel reagent, dicyanomethyl acetate, is used as a nucleophile to give alpha-(N-methyl-N-acetyl)amino acid methyl esters in excellent yield. (Keyword) Aldehydes / Carbon / Imines / Molecular Structure / Oxidation-Reduction (Link to Publication Site) ● Publication site (DOI): 10.1021/ja054010h (Link to Search Site for Scientific Articles) ● PubMed @ National Institutes of Health, US National Library of Medicine (PMID): 16231887 ● Search Scopus @ Elsevier (PMID): 16231887 ● Search Scopus @ Elsevier (DOI): 10.1021/ja054010h (DOI: 10.1021/ja054010h, PubMed: 16231887)
18.	Hisao Nemoto, Tmoaki Kawano, Nobuo Ueji, Nobutaka Sakamoto, Takaaki Araki, Norikazu Miyoshi, Ichiro Suzuki and Masayuki Shibuya : Synthesis of a water-soluble molecular tweezer and a recognition study in an aqueous media, Tetrahedron Letters, Vol.46, No.4, 551-553, 2005. (Keyword) molecule recognition / tweezers / perhydronaphthacene / water soluble / binding constant / hydrophobic interaction / BINDING-PROPERTIES / FUNCTIONAL-GROUPS / COMPLEXATION / CLEFTS / ACID / METHODOLOGY / RECEPTOR / ACCEPTOR / ADENINE / ANALOGS (Link to Publication Site) ● Publication site (DOI): 10.1016/j.tetlet.2004.12.002 (Link to Search Site for Scientific Articles) ● Search Scopus @ Elsevier (DOI): 10.1016/j.tetlet.2004.12.002 (DOI: 10.1016/j.tetlet.2004.12.002)
19.	Kyoko Iwase, Tomoko Tatsuishi, Yumiko Nishimura, Jun-ya Yamaguchi, Yasuo Oyama, Norikazu Miyoshi and Makoto Wada : Cytometric analysis on adverse action of diphenyl ditellurde on rat thymocytes: Cell shrinkage as cytotoxic parameter, Environmental Toxicology, Vol.19, No.6, 614-619, 2004. (Summary) 細胞萎縮を細胞毒性の指標として，有機テルル化合物の毒性評価を行った．ジフェニル·ジテルライドはサブマイクロ濃度でラット胸腺細胞の細胞内カルシウムイオン上昇させ，カスパーゼ依存性にアポトーシスを誘発することが明らかになった．よって，有機テルル化合物の使用·処分には注意を要することが示唆された． (Keyword) Animals / Apoptosis / Benzene Derivatives / Cell Culture Techniques / Cell Size / Dose-Response Relationship, Drug / Flow Cytometry / Male / Organometallic Compounds / Rats / Rats, Wistar / Tellurium / Thymus Gland (Link to Publication Site) ● Publication site (DOI): 10.1002/tox.20070 (Link to Search Site for Scientific Articles) ● PubMed @ National Institutes of Health, US National Library of Medicine (PMID): 15526268 ● Search Scopus @ Elsevier (PMID): 15526268 ● Search Scopus @ Elsevier (DOI): 10.1002/tox.20070 (DOI: 10.1002/tox.20070, PubMed: 15526268)
20.	Keith Smith, Sandra Lock, Gamal A El-Hiti, Makoto Wada and Norikazu Miyoshi : A convenient procedure for bismuth-mediated Barbier-type allylation of aldehydes in water containing fluoride ions., Organic & Biomolecular Chemistry, Vol.2, No.6, 935-938, 2004. (Summary) A new and convenient procedure for synthesis of homoallylic alcs. in generally good to excellent yields has been developed. The bismuth-mediated Barbier-type allylation of aldehydes (arom., aliph., alicyclic and heterocyclic) with allyl bromide has been carried out in water in the presence of fluoride ions. (Keyword) SIMPLE AROMATIC-COMPOUNDS / CARBONYL-COMPOUNDS / AQUEOUS-MEDIA / HOMOALLYLIC ALCOHOLS / ORGANOMETALLIC REACTIONS / SELECTIVE ALLYLATION / HIGHLY EFFICIENT / METALLIC BISMUTH / IN-SITU / LITHIATION (Link to Publication Site) ● Publication site (DOI): 10.1039/b400179f (Link to Search Site for Scientific Articles) ● PubMed @ National Institutes of Health, US National Library of Medicine (PMID): 15007425 ● Search Scopus @ Elsevier (PMID): 15007425 ● Search Scopus @ Elsevier (DOI): 10.1039/b400179f (DOI: 10.1039/b400179f, PubMed: 15007425)
21.	Hisao Nemoto, Hiroe Tsutsumi, Satomi Yuzawa, Xian Peng, Weihui Zhong, Jun Xie, Norikazu Miyoshi, Ichiro Suzuki and Masayuki Shibuya : Highly efficient chiral resolution and determination of absolute configuration of 2-alkanols by using a cyclopenta[b]furan derivative., Tetrahedron Letters, Vol.45, No.8, 1667-1670, 2004. (Summary) The reaction of 3a-benzhydryl-3,3a,4,5-tetrahydro-2H-cyclopenta[b]furan and various 2-alkanols in the presence of a catalytic amt. of pyridinium 4-toluenesulfonate in dichloromethane gave 3a-benzhydryl-6a-(1-methyl-alkoxy)-hexahydrocyclopenta[b]furan in more than 90% chem. yields. The resulting diastereomeric mixt. is easily separable on silica gel chromatog. because of the large Rf value (briefly 0.1). Abs. configuration of the 2-alkanols can be easily estd. by the chem. shifts of 1H and 13C NMR of methyne group of the benzhydryl moiety. (Keyword) chiral resolution / acetal / thin layer chromatography / alkenyl ether / ETHERS / FIELD / ACID (Link to Publication Site) ● Publication site (DOI): 10.1016/j.tetlet.2003.12.104 (Link to Search Site for Scientific Articles) ● CiNii @ National Institute of Informatics (CRID): 1572261551645106560 ● Search Scopus @ Elsevier (DOI): 10.1016/j.tetlet.2003.12.104 (DOI: 10.1016/j.tetlet.2003.12.104, CiNii: 1572261551645106560)
22.	Norikazu Miyoshi, Koji Kamiura, Hiromi Oka, Akiko Kita, Rika Kuwata, Daitetsu Ikehara and Makoto Wada : The Barbier-type alkylation of aldehydes with alkyl halides in the presence of metallic strontium., Bulletin of the Chemical Society of Japan, Vol.77, No.2, 341-345, 2004. (Summary) In the presence of metallic strontium, the Barbier-type alkylation of aldehydes with alkyl iodides proceeded smoothly to afford secondary alcs., e.g., I, in moderate to good yields. The unusual addn. reaction of Et benzoate with tert-Bu iodide gave 4-tert-butylbenzoate in good yield. Using strontium isopropoxide, the Meerwein-Ponndorf-Verley-type redn. of the aldehyde proceeded smoothly under reflux conditions in 2-propanol. (Link to Publication Site) ● Publication site (DOI): 10.1246/bcsj.77.341 (Link to Search Site for Scientific Articles) ● CiNii @ National Institute of Informatics (CRID): 1521699230020170880 ● Search Scopus @ Elsevier (DOI): 10.1246/bcsj.77.341 (DOI: 10.1246/bcsj.77.341, CiNii: 1521699230020170880)
23.	Norikazu Miyoshi, Mami Nishio, Shun-suke Murakami, Tomohiro Fukuma and Makoto Wada : 4) A Convenient One Pot Allylation of Aldehydes with Allylic Halides Prepared in situ from Allylic Alcohols in the Presence of Metallic Bismuth, Bulletin of the Chemical Society of Japan, Vol.78, 689-692, 2000.
24.	Yasuo Oyama, Mami Nakata, Mineshi Sakamoto, Lumi Chikahisa, Norikazu Miyoshi and Masaya Satoh : Methylmercury toxicity in rat brain neurons: modificatons by compounds possessing SH-group and comparison with dimethylmercury, N-ethylmaleimide, and ionomycin, Environmental Toxicology and Pharmacology, Vol.6, 221-227, 1998. (Keyword) methylmercury
25.	Lumi Chikahisa, Yasuo Oyama, Yoko Iguchi, Eisuke Okazaki, Norikazu Miyoshi, Masaya Satoh and Yuji Yamada : Effects of triphenyltin on growth and viability of K562 leukemia cells, Environmental Toxicology and Pharmacology, Vol.6, 209-215, 1998. (Keyword) triphenyltin
26.	Makoto Wada, Munekazu Honna, Yoshihiro Kuramoto and Norikazu Miyoshi : A Grignard-Type Addition of an Allyl Unit to Carbonyl Compounds Containing a Carboxyl Group by Using BiCl3-Zn(0)-Allyl Bromide., Bulletin of the Chemical Society of Japan, Vol.70, No.9, 2265-2267, 1997. (Summary) In the presence of BiCl3-Zn(0), nearly equimolar amts. of allyl bromide reacted with carbonyl compds. contg. a carboxyl group to afford the corresponding homoallylic alcs. having a carboxyl group or the intramol. dehydrated lactones in good yields.
27.	Makoto Wada, Toshikazu Takahashi, Terutomo Domae, Tomohiro Fukuma, Norikazu Miyoshi and Keith Smith : Asymmetric trimethylsilylcyanation of aldehydes utilizing chiral bismuth compounds. A frontier in bismuth mediated synthetic reactions., Tetrahedron: Asymmetry, Vol.8, No.23, 3939-3946, 1997. (Summary) Bismuth(III) chloride (BiCl3) was found to work efficiently as a versatile catalyst for cyanation of aldehydes with trimethylsilyl cyanide to afford the corresponding cyanohydrins in high yields. Triphenylbismuthan (Ph3Bi) is also effective. The reaction has been applied to the asym. cyanation of a variety of aldehydes in high yields with moderate to good enantioselectivities by use of a chiral bismuth catalyst prepd. in situ from BiCl3 and (2R,3R)-(+)-diethyl tartrate.
28.	Norikazu Miyoshi, Seiji Takeuchi and Yoshiaki Ohgo : Regioselective allylation of ketenes promoted by SmI2., Bulletin of the Chemical Society of Japan, Vol.67, No.2, 445-451, 1994. (Summary) Ketenes react with various allylic halides mediated by 2 equiv SmI2 to afford allylated ketones in good yields. In the reaction with -substituted allylic halides, the regioselectivity is influenced by the olefinic geometry of allylic halides. By using -substituted (E)-allylic halides, allylation occurs predominantly at the less hindered site ( -position) of allylic groups and the tendency was enhanced by the addn. of HMPA.
29.	Seji Takeuchi, Akiko Ohira, Norikazu Miyoshi, Hajime Mashio and Yoshiaki Ohgo : Enantioselective protonation of samarium enolates by a C2-symmetric chiral diol., Tetrahedron: Asymmetry, Vol.5, No.9, 1763-1780, 1994. (Summary) High enantioselectivity (up to 97% ee) has been achieved in the protonation of samarium enolates which were generated by SmI2-mediated cross-coupling reaction between unsym. dialkylketenes and allyl iodide, using C2-sym. chiral diol (S,S)-o-C6H4(CH2OCH2CHPhOH)2 as a proton source. The stereochem. of enolate formation and of the enantioselective protonation is discussed.
30.	Seiji Takeuchi, Norikazu Miyoshi, Kenji Hirata, Haruyoshi Hayashida and Yoshiaki Ohgo : Asymmetric synthesis of benzoin by samarium diiodide-mediated enantioselective protonation., Bulletin of the Chemical Society of Japan, Vol.65, No.7, 2001-2003, 1992. (Summary) Samarium (Z)-1,2-diphenylethen-1,2-diolate, which is considered to be an intermediate of a SmI2-mediated redn. of benzil, was protonated enantioselectively by quinidine to afford (R)-benzoin in 91% ee. It was found that quenching the unreacted enediolate with oxygen was crucial to obtain high enantioselectivity. The configuration of the samarium enediolate was confirmed by isolating (Z)-O,O'-diacetyl-1,2-diphenylethen-1,2-diol.
31.	Seiji Takeuchi, Yoshiaki Ohgo, Norikazu Miyoshi, Gi Chung Shin and Yasuchika Yonezawa : Asymmetric reactions. XVI. Asymmetric synthesis of a piperazine alkaloid., Heterocycles, Vol.31, No.11, 2073-2708, 1990. (Summary) Piperazine alkaloid, (2S,5S)-2,5-dibenzyl-1,4-dimethylpiperazine (I) was synthesized by redn. of (3S,6S)-3,6-dibenzyl-1,4-dimethyl-2,5-piperazinedione which was prepd. by a catalytic asym. hydrogenation of the corresponding 3,6-dibenzylidene deriv.

Academic Paper (Unrefereed Paper):

1.	Yoshihiko Okada, Yasuo Oyama, Toshiko Ueha-Ishibashi, Kaori Kanemaru, Norihiko Akaike, Norikazu Miyoshi and Masaya Satoh : Cytotoxic action of tri-n-butyltin hydride, a nucleaphilic triorganotin, on rat thymocytes: a flow cytometric study, Natural Science Research, Vol.14, 21-34, 2001. (Keyword) tri-n-butyltin
2.	Yuko Yamazaki, Mami Nakata, Noriko Kajita, Megumi Funai, Sachi Noguchi, Yasuo Oyama, Norikazu Miyoshi and Masaya Satoh : Effects of organic and inorganic mercuries on growth and viability of K562 human leukemia cells, Natural Science Research, Vol.12, 15-26, 1999. (Keyword) heavy metal

Academic Letter:

1.	Norikazu Miyoshi, Asaoka Masashi, Miyazaki Yasuaki, Tajima Takahiro, Makoto Kikuchi and Makoto Wada : The Convenient and Useful Esterification of Bulky Tertiary Alcohols Using Strontium Compounds, Chemistry Letters, Vol.2012, No.41, 35-36, 2012. (Keyword) organic chemistry (Link to Publication Site) ● Publication site (DOI): 10.1246/cl.2012.35 (Link to Search Site for Scientific Articles) ● CiNii @ National Institute of Informatics (CRID): 1360002219111680384 ● Search Scopus @ Elsevier (DOI): 10.1246/cl.2012.35 (DOI: 10.1246/cl.2012.35, CiNii: 1360002219111680384)
2.	Norikazu Miyoshi, Tadashi Kohno, Makoto Wada, S. Matsunaga, I. Mizota and Makoto Shimizu : Reductive Self-coupling Reaction of Imines and Aldehydes Induced by Strontium Metal, Chemistry Letters, Vol.38, No.10, 984-985, 2009. (Keyword) organic chemistry (Link to Publication Site) ● Publication site (DOI): 10.1246/cl.2009.984 (Link to Search Site for Scientific Articles) ● CiNii @ National Institute of Informatics (CRID): 1360846644041476864 ● Search Scopus @ Elsevier (DOI): 10.1246/cl.2009.984 (DOI: 10.1246/cl.2009.984, CiNii: 1360846644041476864)
3.	Norikazu Miyoshi, Tsuyoshi Matsuo, Mariko Mori, Aki Matsui, Makoto Kikuchi, Makoto Wada and Masahiko Hayashi : A New Synthetic Method for Para Alkylation of Benzoic Acids Using Metallic Strontium and Alkyl Iodide, Chemistry Letters, Vol.38, No.10, 996-997, 2009. (Keyword) organic chemistry (Link to Publication Site) ● Publication site (DOI): 10.1246/cl.2009.996 (Link to Search Site for Scientific Articles) ● CiNii @ National Institute of Informatics (CRID): 1570572700907554176 ● Search Scopus @ Elsevier (DOI): 10.1246/cl.2009.996 (DOI: 10.1246/cl.2009.996, CiNii: 1570572700907554176)
4.	Norikazu Miyoshi, Tsuyoshi Matsuo, Masashi Asaoka, Aki Matsui and Makoto Wada : A New Synthetic Method for Methyl Ketones from Carboxylic Acids Using Metallic Strontium and Methyl Iodide, Chemistry Letters, Vol.36, No.1, 28-29, 2007. (Link to Publication Site) ● Publication site (DOI): 10.1246/cl.2007.28 (Link to Search Site for Scientific Articles) ● CiNii @ National Institute of Informatics (CRID): 1360565169064401280 ● Search Scopus @ Elsevier (DOI): 10.1246/cl.2007.28 (DOI: 10.1246/cl.2007.28, CiNii: 1360565169064401280)
5.	Norikazu Miyoshi, Tsuyoshi Matsuo and Makoto Wada : The Chemistry of Alkylstrontium Halide Analogue Part 2: Barbier-Type Dialkylation of Esters with Alkyl Halides, European Journal of Organic Chemistry, Vol.2005, No.20, 4253-4255, 2005. (Link to Publication Site) ● Publication site (DOI): 10.1002/ejoc.200500484 (Link to Search Site for Scientific Articles) ● Search Scopus @ Elsevier (DOI): 10.1002/ejoc.200500484 (DOI: 10.1002/ejoc.200500484)
6.	Norikazu Miyoshi, Ikehara Daitetsu, Kohno Tadashi, Matsui Aki and Makoto Wada : The Chemistry of Alkylstrontium Halide Analogues: Barbier-type Alkylation of Imines with Alkyl Halides, Chemistry Letters, Vol.34, No.6, 760-761, 2005. (Link to Publication Site) ● Publication site (DOI): 10.1246/cl.2005.760 (Link to Search Site for Scientific Articles) ● CiNii @ National Institute of Informatics (CRID): 1570572700194508928 ● Search Scopus @ Elsevier (DOI): 10.1246/cl.2005.760 (DOI: 10.1246/cl.2005.760, CiNii: 1570572700194508928)
7.	Sandra Jacqueline Lock, Norikazu Miyoshi and Makoto Wada : Solvent-free Imino-Aldol Three-component Couplings on a Conveniently-prepared and Reusable Phosphoric Acid-Silica Gel Support, Chemistry Letters, Vol.33, No.10, 1308-1309, 2004. (Link to Publication Site) ● Publication site (DOI): 10.1246/cl.2004.1308 (Link to Search Site for Scientific Articles) ● CiNii @ National Institute of Informatics (CRID): 1390282679558864256 ● Search Scopus @ Elsevier (DOI): 10.1246/cl.2004.1308 (DOI: 10.1246/cl.2004.1308, CiNii: 1390282679558864256)
8.	Tomohiro Fukuma, Sandra Lock, Norikazu Miyoshi and Makoto Wada : Water Accelerated Allylation of Aldehydes by Using Water Tolerant Grignard-Type Allylating Agents from Allylmagnesium Chloride and Various Metallic Salts, Chemistry Letters, Vol.2002, No.3, 376-377, 2002. (Summary) Some water-tolerant allylating agents prepared in situ from allylmagnesium chloride and bismuth trichloride, tin tetrachloride, tin dichloride, antimony trichloride, indium trichloride, or nickel dichloride reacted with aldehydes in THF-H2O to afford the desired homoallylic alcohols in good yields. The present reaction proceeded more smoothly than that under non-aqueous media. (Link to Search Site for Scientific Articles) ● CiNii @ National Institute of Informatics (CRID): 1571417124671697152 ● Summary page in Scopus @ Elsevier: 2-s2.0-0036012146 (CiNii: 1571417124671697152, Elsevier: Scopus)
9.	Ryouich Hiroi, Norikazu Miyoshi and Makoto Wada : Organic Solvent-Free One-Pot Reduction of Imines Generated in situ from Aldehydes and Aniline by Tributyltin Hydride on Silica Gel, Chemistry Letters, Vol.2002, 274-275, 2002. (Summary) Imines generated in situ from aldehydes and aniline can be reduced using tributyltin hydride on silica gel under solvent-free conditions to provide te corresponding amines in good yields.
10.	Makoto Wada, Sonoe Nagayama, Kaori Mizutani, Ryouichi Hiroi and Norikazu Miyoshi : Bismuth Trichloride Catalyzed Efficient Reductive Etherification of Carbonyl Compounds with Alcohols: A Novel Method for Preparation of Symmetrical and Unsymmetrical Ethers, Chemistry Letters, Vol.2002, 248-249, 2002. (Summary) The reductive homocoupling of a carbonyl compound and heterocoupling of a carbonyl compound with a non-protected alcohol were both effected smoothly at room temperature with triethylsilane in the presence of a catalytic amount of bismuth trichloride to afford the corresponding ethers in good yields. (Link to Search Site for Scientific Articles) ● Summary page in Scopus @ Elsevier: 2-s2.0-0036003206 (Elsevier: Scopus)
11.	Makoto Wada, Tomohiro Fukuma, Mika Morioka, Toshikazu Tkahashi and Norikazu Miyoshi : A novel aqueous Barbier-Grignard-type allylation of aldehydes in a Mg/BiCl3 bimetallic system., Tetrahedron Letters, Vol.70, No.9, 2265-2267, 1997. (Summary) In the presence of BiCl3-Zn(0), nearly equimolar amts. of allyl bromide reacted with carbonyl compds. contg. a carboxyl group to afford the corresponding homoallylic alcs. having a carboxyl group or the intramol. dehydrated lactones in good yields.
12.	Norikazu Miyoshi, Tomohiro Fukuma and Makoto Wada : The cross-coupling reaction of aldehydes with -diketones by the use of bismuth trichloride and metallic zinc., Chemistry Letters, Vol.1995, No.11, 999-1000, 1995. (Summary) In the presence of bismuth trichloride and metallic zinc, -diketones react with aldehydes in THF under reflux to afford the corresponding , -dihydroxy ketones in moderate to good yields. The reaction takes place even in aq. media.
13.	Norikazu Miyoshi, Seiji Takeuchi and Yoshiaki Ohgo : The SmI2 mediated cross-coupling reaction of aldehydes with a-diketones in their aqueous forms., Chemistry Letters, Vol.1993, No.12, 2129-2132, 1993. (Summary) By the use of samarium diiodide (SmI2), a cross-coupling reaction of aldehydes with -diketones smoothly proceeds in the presence of water to give the corresponding adducts in moderate to good yield. Thus, cross-coupling reaction of MeCOCHO with PhCH2CHO in THF and H2O contg. SmI2 gave 39:61 isomeric ratio of anti- and syn-PhCH2CHOHCHOHCOMe in 64% yield. In this reaction, it is possible to use the substrates such as phenylglyoxal monohydrate, aq. methylglyoxal, formalin, and aq. -chloroacetaldehyde.
14.	Norikazu Miyoshi, Seiji Takeuchi and Yoshiaki Ohgo : A facile synthesis of 2,3-dihydroxy ketones from 1,2-diketones and aldehydes using samarium diiodide., Chemistry Letters, Vol.1993, No.6, 959-962, 1993. (Summary) In the presence of samarium diiodide, 1,2-diketones R1COCOR2 react with aldehydes R3CHO in THF to afford the corresponding 2,3-dihydroxy ketones anti- and syn-R3CH(OH)CR1(OH)COR2 (e.g., R1 = R2 = Me, R3 = PhCH2CH2) in good yields with moderate diastereoselectivity (anti preferred). The reaction of unsym. 1,2-diketones with aldehydes gives the products with high regioselectivities.
15.	Seiji Takeuchi, Norikazu Miyoshi and Yoshiaki Ohgo : Asymmetric synthesis of ketones by samarium diiodide-mediated allylation or benzylation of ketenes followed by enantioselective protonation., Chemistry Letters, Vol.1992, No.2, 551-554, 1992. (Summary) SmI2-mediated allylation or benzylation of alkyl aryl ketenes followed by enantioselective protonation with (S,S)-o-[PhCH(OH)CH2OCH2]2C6H4 gave the corresponding ketones in 61-91% ee.
16.	Koichi Narasaka, Norikazu Miyoshi, Kazunori Iwakura and Tatsuo Okauchi : The addition reaction of -keto carboxylic acids to olefinic compounds by the use of Mn(III) tris(2-pyridinecarboxylate) as an oxidant., Chemistry Letters, Vol.1989, No.12, 2169-2172, 1989. (Summary) Intermol. addn. reactions of radical species generated from -keto carboxylic acids to olefinic compds. such as a silyl enol ether, a ketene dithioacetal and an enamine proceed selectively by the use of manganese(III) tris(2-pyridinecarboxylate) (I) as an oxidant. E.g., BzCHMeCH2Bz was obtained in 70% yield from reaction of BzCHMeCO2H with PhC(:CH2)OSiMe3 in DMF in the presence of I.
17.	Koichi Narasaka, Fumihiko Kanai, Makoto Okudo and Norikazu Miyoshi : Kinetic resolution of -arylcarboxylic acid derivatives by a catalytic use of a chiral titanium alkoxide., Chemistry Letters, Vol.1989, No.7, 1187-1190, 1989. (Summary) Kinetic resoln. of racemic -aryl carboxylic acids is successfully achieved by a catalytic use of Ti(OCHMe2)4 and a chiral 1,4-diol in the reaction of the corresponding 2-pyridinethiol esters and Me2CHOH. Thus, reaction of ( )-EtCHPhCOSR (R = 2-pyridyl) with 10 mol. % Ti(OCHMe2)4, 11 mol. % diol I, and 5 equiv Me2CHOH in PhMe gave 69% (based on 1/2 equiv of the thio ester) (R)-EtCHPhCO2CHMe2.
18.	Teruaki Mukaiyama, Masahiro Ohshima and Norikazu Miyoshi : An efficient and convenient method for the asymmetric allylation of aldehydes with allyltrimethylsilane catalyzed by diphenylboryl triflate., Chemistry Letters, Vol.1987, No.6, 1124-1127, 1987. (Summary) Using catalytic amts. of diphenylboryl triflate, aldehydes reacted with (S)-1-phenyl-1-trimethylsilyloxyethane and Me3CSiCH2CH:CH2 to give the chiral homoallyl ethers,e.g., PhCH2O(CH2)2CH(OCHMePh)CH2CH:CH2, in good yields with high stereoselectivities.
19.	Masahiro Ohshima, Norikazu Miyoshi and Teruaki Mukaiyama : An efficient method for the kinetic resolution of cyclic dl-dicarboxylic anhydrides catalyzed by diphenylboryl triflate., Chemistry Letters, Vol.1987, No.6, 1233-1236, 1987. (Summary) In the presence of CF3SO3BPh2, the kinetic resoln. of cyclic d1-dicarboxylic anhydrides is effectively achieved by (R)-PhCH(OBPh2)CH2OMe as the chiral source.
20.	Teruaki Mukaiyama, Norikazu Miyoshi, Jun-ichi Kato and Masahiro Ohshima : A facile method for the oxidation of aldehydes to carboxylic acids via acetal-type diperoxides., Chemistry Letters, Vol.1986, No.8, 1385-1388, 1986. (Summary) In the presence of a catalytic amt. of Ph3CClO4, RCHO [R = Ph, PhCH2CH2, PhCH2OCH2CH2, CH2:CH(CH2)8, 2-BrC6H4, 4-MeSC6H4] react with Me3SiOOCMe3 to give RCH(OOCMe3)2 (I) in good yields. Reactions of I with piperidine at 90 or with aq. CuSO4 and L-ascorbic acid at room temp. gave RCO2H in good yields.
21.	Teruaki Mukaiyama, Jun-ichi Kato, Norikazu Miyoshi and Nobuharu Iwasawa : A novel and useful method for the preparation of methyl esters from dimethyl acetals., Chemistry Letters, Vol.1985, No.8, 1255-1258, 1985. (Summary) In the presence of a catalytic amt. of trityl perchlorate, acetal-type peroxides RCH(OMe)OOCMe3 [R = PhCH2, Ph(CH2)2, PhCHMe, octyl, nonyl, CH2:CH(CH2)8] were prepd. from di-Me acetals and Me3COOSiMe3 in 85-90% yields. The peroxides were then converted to the corresponding Me esters in 84-94% yields by pyrolysis.

Review, Commentary:

1.	Norikazu Miyoshi : The development of the new synthetic methods using metallic strontium, Chemical Industry, Vol.61, No.9, 35-38, Sep. 2010. (Link to Search Site for Scientific Articles) ● CiNii @ National Institute of Informatics (CRID): 1521417755727994752 (CiNii: 1521417755727994752)
2.	Norikazu Miyoshi and Makoto Wada : The Barbier-Type Alkylation of Carbonyl Compounds with Alkyl Iodides Using Metallic Strontium, Fine chemicals, Vol.36, No.9, 28-36, Aug. 2007. (Link to Search Site for Scientific Articles) ● CiNii @ National Institute of Informatics (CRID): 1521699230264172672 (CiNii: 1521699230264172672)
3.	Norikazu Miyoshi, Ikehara Daitetsu, Matsuo Tsuyoshi, Kohno Tadashi, Matsui Aki and Makoto Wada : The Barbier-Type Alkylation of Carbonyl Compounds with Alkyl Halides Using Metallic Strontium, Journal of Synthetic Organic Chemistry, Japan, Vol.64, No.8, 845-852, Aug. 2006. (Summary) Organometallic compounds comprise some of the most versatile reagents in organic synthesis, and among them are organometallic compounds of alkaline-earth elements. Numerous reports have been published on the Grignard (or Barbier) reaction using metallic magnesium and alkyl halides. Furthermore, there are various reports on the preparation and reactivity of the organometallic compounds of calcium and barium. In contrast, fewer studies on the preparation and reactivity of organostrontium compounds were found in the literature. As the results on our investigation, it's found that in the presence of metallic strontium, the Barbier-type alkylation of aldehydes with alkyl iodides proceeded smoothly at-15°C under an argon atmosphere to afford the corresponding alkylated alcohols in moderate to good yields. The Barbier-type alkylation of imines with alkyl iodides also took place smoothly at room temperature under an argon atmosphere to give the corresponding alkylated amines in good yields. Aromatic aldimines reacted with metallic strontium in the presence of a catalytic amount of iodine to obtain the self-coupling products in good yields. Furthermore, the Barbier-type alkylation of esters with alkyl iodides proceeded smoothly at room temperature under an argon atmosphere to afford the corresponding dialkylated alcohols in good yields. (Keyword) strontium / Barbier-type reaction / alkylation / aldehyde / imine / ester / carboxylic acid / p-alkylation (Link to Publication Site) ● Publication site (DOI): 10.5059/yukigoseikyokaishi.64.845 (Link to Search Site for Scientific Articles) ● CiNii @ National Institute of Informatics (CRID): 1390001205312887040 ● Summary page in Scopus @ Elsevier: 2-s2.0-33750700478 (DOI: 10.5059/yukigoseikyokaishi.64.845, CiNii: 1390001205312887040, Elsevier: Scopus)
4.	Makoto Wada and Norikazu Miyoshi : Organic Synthesis by Using Bismuth and Tin Compounds: Synthetic Organic Reaction in Aqueous Media, Journal of Synthetic Organic Chemistry, Japan, Vol.57, No.8, 689-697, Aug. 1999. (Summary) A review with 36 refs. on (1) Grignard-type addn. of allyl unit to carbonyl compds. contg. CO2H by using BiCl3-Zn-allyl bromide, (2) allylation of aldehydes by using allylic alcs. in the presence of Bi, (3) a novel aq. Barbier-Grignard-type allylation of aldehydes in a Mg/BiCl3 bimetal system, (4) allylation of carbonyl compds. by using allyl Grignard reagent and various metallic salts in aq. media, (5) allylation of aldehydes by using allyltin compds. in aq. media, (6) asym. allylation of carbonyl compds. by using tetraallyltin, (7) Bi-mediated allylation of unprotected carbohydrates, (8) ether synthesis by using a catalytic amt. of BiCl3 and Et3SiH, (9) asym. cyanation of aldehydes promoted by a catalytic amt. of chiral Bi compd., and (10) redn. of aldehydes by using Bu3SnH in MeOH or H2O.

Proceeding of International Conference:

1.	Kobatake Miho, Norikazu Miyoshi and Masaharu Ueno : Total synthesis of Riccardin C using one-pot tandem coupling reactions, The 2021 International Chemical Congress of Pacific Basin Societies (Pacifichem), Honolulu Hawaii, USA (Online), Honolulu Hawaii, USA, Dec. 2021.
2.	Masaharu Ueno, Kazuki Tani and Norikazu Miyoshi : Development of Multicomponent, One-pot Sonogashira-Suzuki Tandem Coupling Reaction in Water, The 2021 International Chemical Congress of Pacific Basin Societies (Pacifichem), Honolulu Hawaii, USA, Honolulu Hawaii, USA, Dec. 2021.
3.	Norikazu Miyoshi, Yasuaki Miyazaki, Daisuke Kanehiro, Yuka Yamaguchi, Satoshi D. Ohmura and Makoto Wada : The Convenient and Useful Sr-mediated Superior Alkylating Agents for Esters or Bulky Ketones, Meeting Abstract of XXVI Interernational Conference on Organometallic Chemistry, Jul. 2014.
4.	Norikazu Miyoshi, Tsuyoshi Matsu, Masashi Asaoka, Mariko Mori, Aki Matsui and Makoto Wada : Strontium-Mediated Alkylation of Carboxylic Acids and Salts, OMCOS14, P486, Nara, Aug. 2007.
5.	Norikazu Miyoshi, Daitetsu Ikehara, Tadashi Kouno, Tsuyoshi Matsuo, Aki Matsui and Makoto Wada : The Chemistry of Alkylstrontium Halide Analogues: Barbier-Type Alkylation of Carboxylic Derivatives, OMCOS13, P310, Geneva, Jul. 2005.
6.	Norikazu Miyoshi : The Chemistry of Alkylstrontium Halide Analogues: The Barbier-Tpye Alkylation of Carbonyl Compounds, Proceeding of Choshu-London Memorial Symposium in Organic Chemistry, 1-7, Yamaguchi, Mar. 2005.
7.	Norikazu Miyoshi, Daitetsu Ikehara, Tadashi Kouno, Tsuyoshi Matsuo and Makoto Wada : Chemistry of Alkylstrontium Halide Analogues: The Barbier-Type Alkylation of Carbonyl Compounds, International Symposium on Chemicals and Pharmaceuticals, Vol.2004, 17-18, Guangzhou, Dec. 2004.
8.	Norikazu Miyoshi, Daitetsu Ikehara, Tadashi Kouno, Tsuyoshi Matsuo and Makoto Wada : Alkylation of Aldehydes and Imines Using Metallic Strontium and Alkyl Iodides, International Symposium on Catalysis and Fine Chemicals 2004, Vol.2004, P-20, Hong Kong, Dec. 2004.

Proceeding of Domestic Conference:

1.	KAMADA Chisato, Ryosuke Shimoda, Masaharu Ueno and Norikazu Miyoshi : ストロンチウムアルコキシド触媒を用いる簡便かつ有用なエステル交換反応の開発, 日本化学会第104春季年会,日本大学理工学部(千葉),公演番号 E1111-4pm-04, Mar. 2024.
2.	Tatsuya Watanabe, Masaharu Ueno and Norikazu Miyoshi : 金属ストロンチウムを用いるアミド化合物のアルデヒドへの還元反応, 日本化学会第104春季年会,日本大学理工学部(千葉),公演番号 E1111-4pm-03, Mar. 2024.
3.	Masaharu Ueno, TASHIMA Miku and Norikazu Miyoshi : HPCB-5, 日本化学会第104春季年会,日本大学理工学部(千葉),公演番号 E1143-2pm-08, Mar. 2024.
4.	MIYOSHI Aki, Satoshi D. Ohmura, Norikazu Miyoshi and Masaharu Ueno : 環境調和型ワンポット・タンデムカップリング反応を用いた光機能性化合物の効率的合成及びその評価, 日本化学会第104春季年会,日本大学理工学部(千葉),公演番号 E1143-2pm-02, Mar. 2024.
5.	MIYOSHI Aki, Miho Kobatake, Norikazu Miyoshi and Masaharu Ueno : ワンポット・タンデムカップリング反応を駆使した天然物Riccardin類の効率的かつ網羅的合成法の開発, 日本化学会第104春季年会,日本大学理工学部(千葉),公演番号 E1143-2am-02, Mar. 2024.
6.	Tatsuya Watanabe, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : Reduction of amides with strontium metal, 日本化学会第103春季年会,東京理科大学(千葉),公演番号 K404-4pm-06, 2023年3月., Mar. 2023.
7.	AKI Miyoshi, Norikazu Miyoshi and Masaharu Ueno : Environmentally benign and efficient one-pot synthesis of polyaryl compounds by the tandem coupling reaction controlled on reaction temperatures, 日本化学会第103春季年会,東京理科大学(千葉),公演番号 P4-2am-33, 2023年3月., Mar. 2023.
8.	Kohki Kimura, Norikazu Miyoshi and Masaharu Ueno : ビスマス塩を触媒とするアルデヒドの環境調和型酸化反応の開発, 2022年日本化学会中国四国支部大会,広島大学(広島),講演番号2PB-11, Nov. 2022.
9.	Yu Kawakami, Norikazu Miyoshi and Masaharu Ueno : セラミド輸送阻害剤HPA-12類縁体の効率的合成, 2022年日本化学会中国四国支部大会,広島大学(広島),講演番号2PB-10, Nov. 2022.
10.	AKI Miyoshi, Kazuki Tani, Norikazu Miyoshi and Masaharu Ueno : ワンポットタンデムカップリング反応によるポリアリール化合物の環境調和型効率的合成, 2022年日本化学会中国四国支部大会,広島大学(広島),講演番号2K-10, Nov. 2022.
11.	Aki Miyoshi, Yasuaki Miyazaki, Shigeki Kubo, Masaharu Ueno and Norikazu Miyoshi : 金属ストロンチウムを用いる新しい形のシリルエーテル化反応の開発, 日本化学会第102春季年会,オンライン開催,公演番号 D202-4pm-07, Mar. 2022.
12.	Norikazu Miyoshi : 高大連携事業を通じた理系人材育成, Abstracts of Annual Meeting of Japan Chemical Society, Vol.2022, B101-3, Mar. 2022.
13.	Miho Kobatake, Norikazu Miyoshi and Masaharu Ueno : Riccardin Cの全合成をモデルとした効率的なワンポットタンデムカップリング反応の研究-ユニット合成の簡便さを考慮した適切な炭素-炭素切断位置及び組み合わせる官能基の設計-, 日本化学会第102春季年会,オンライン開催,公演番号 K5-2am-04, Mar. 2022.
14.	Masaharu Ueno, TANAKA Takumi, Satoshi D. Ohmura and Norikazu Miyoshi : 照射波長によるスチルバゾール類光異性化/環化反応の厳密な制御, 日本化学会第101春季年会,オンライン開催,公演番号 A17-4am-08, Mar. 2021.
15.	Hiroaki Nakamura, Haruka Takahashi, Masaharu Ueno and Norikazu Miyoshi : 金属ストロンチウムを用いたアセチレン骨格を複数持つ化合物を構築することによる短工程多置換イソベンゾフラノン合成手法の開発, 日本化学会第101春季年会,オンライン開催,公演番号 A15-1vn-10, Mar. 2021.
16.	Taiga Noda, Shohdai Kimura, Shigeki Kubo, Masaharu Ueno, Satoshi D. Ohmura and Norikazu Miyoshi : 金属ストロンチウムを用いる種々のアミド化合物への半アルキル化反応の応用, 日本化学会第101春季年会,オンライン開催,公演番号 A15-1vn-09, Mar. 2021.
17.	KOBATAKE Miho, Norikazu Miyoshi and Masaharu Ueno : ワンポットタンデムカップリング反応を用いた環境調和型Riccardin Cの全合成研究, 日本化学会第101春季年会,オンライン開催,公演番号 A19-2pm-06, Mar. 2021.
18.	Mami Fujita, Takahiro Nishizawa, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : The covenient synthesis of functional silicic compounds via strontium-metallacycle intermediates and their photophysical properties with the substitution effects, 日本化学会第100春季年会, 東京理科大学(千葉), 公演番号3H8-49, Mar. 2020.
19.	Masaharu Ueno, Miho Kobatake, Satoshi D. Ohmura and Norikazu Miyoshi : Synthetic study of Riccardin C using one-pot tandem coupling reactions, 日本化学会第100春季年会, 東京理科大学(千葉), 公演番号3B5-10, Mar. 2020.
20.	Masaharu Ueno, Satoshi D. Ohmura and Norikazu Miyoshi : Study of the control of photoisomerization/aromatization of stilbazoles, 日本化学会第100春季年会, 東京理科大学(千葉), 公演番号1C4-46, Mar. 2020.
21.	Satoshi D. Ohmura, Taiga Noda, Masaharu Ueno and Norikazu Miyoshi : Luminescent properties of N-arylcarbazole derivatives with alkyl chains on the benzene ring, 日本化学会第100春季年会, 東京理科大学(千葉), 公演番号1C3-57, Mar. 2020.
22.	Taiga Noda, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : N-アリールカルバゾール誘導体へのアルキル基の導入による立体効果に基づく発光特性変化の検討, 2019年度第3回日本プロセス化学会東四国地区フォーラムセミナー, Jan. 2020.
23.	Hiroaki Nakamura, Haruka Takahashi, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : 多置換イソベンゾフラノン合成を指向した金属ストロンチウムを用いるアセチレン骨格を二つ以上持つ化合物の合成手法の検討, 2019年度第3回日本プロセス化学会東四国地区フォーラムセミナー, Jan. 2020.
24.	Taiga Noda, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : N-アリールカルバゾール誘導体におけるアルキル基の導入による立体効果に基づく発光特性の検討, 2019年日本化学会中国四国支部大会, 徳島大学(徳島), 講演番号1P-029, Nov. 2019.
25.	Hiroaki Nakamura, Haruka Takahashi, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : 多置換イソベンゾフラノン合成を指向した金属ストロンチウムを用いるアセチレン骨格を二つ持つ化合物の合成手法の検討, 2019年日本化学会中国四国支部大会, 徳島大学(徳島), 講演番号1P-026, Nov. 2019.
26.	Mami Fujita, Takahiro Nishizawa, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : ストロンチウム-メタラサイクル中間体を用いた機能性ケイ素化合物を指向した簡便な合成手法の開発, 2019年日本化学会中国四国支部大会, 徳島大学(徳島), 講演番号1F-07, Nov. 2019.
27.	Kazuya Hirata, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : A study of alkylation into N-atom contained disk-like molecules by using metallic strontium, 日本化学会第99春季年会, 甲南大学(兵庫), 講演番号3PC-057, Mar. 2019.
28.	Satoshi D. Ohmura, Shohdai Kimura, Masaharu Ueno and Norikazu Miyoshi : A study of transformation of carbonyl/amide moieties by metallic strontium as an electron source, 日本化学会第99春季年会, 甲南大学(兵庫), 講演番号3PC-056, Mar. 2019.
29.	Ryo Kusaka, Satoshi D. Ohmura, Norikazu Miyoshi and Masaharu Ueno : Development of environment friendly organic reactions using bismuth compounds as a catalyst, 日本化学会第99春季年会, 甲南大学(兵庫), 講演番号3PC-027, Mar. 2019.
30.	Masaharu Ueno, Mayu Okumura, Satoshi D. Ohmura and Norikazu Miyoshi : Study of the one-way photoisomerization of stilbazoles, 日本化学会第99春季年会, 甲南大学(兵庫), 講演番号1B4-42, Mar. 2019.
31.	Ryo Kusaka, Satoshi D. Ohmura, Norikazu Miyoshi and Masaharu Ueno : 有機ビスマスを含む協奏機能触媒を用いた新規カップリング反応の研究, 2018年日本化学会中国四国支部大会，愛媛大学城北キャンパス(愛媛)，講演番号2G-08, Nov. 2018.
32.	Yusuke Ishii, Takahiro Nishizawa, Sawa Tateda, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : 金属ストロンチウムを用いる嵩高い含窒素化合物の合成手法の開発, 2018年日本化学会中国四国支部大会，愛媛大学城北キャンパス(愛媛)，講演番号2G-07, Nov. 2018.
33.	Shodai Kimura, Shigeki Kubo, Takahiro Nishizawa, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : 金属ストロンチウムを用いるラジカル種の生成とその応用, 2018年日本化学会中国四国支部大会，愛媛大学城北キャンパス(愛媛)，講演番号1P-030, Nov. 2018.
34.	Norikazu Miyoshi, Takahiro Nishizawa, Saki Kitakata, Satoshi D. Ohmura and Masaharu Ueno : ストロンチウム-メタラサイクル中間体の構造推定とその反応性に関する研究, 第29回基礎有機化学討論会，東京工業大学大岡山キャンパス(東京)，講演番号3C08, Sep. 2018.
35.	Satoshi D. Ohmura, Shodai Kimura, Shigeki Kubo, Masaharu Ueno and Norikazu Miyoshi : 金属ストロンチウムを反応剤として用いる選択的官能基変換, 第29回基礎有機化学討論会，東京工業大学大岡山キャンパス(東京)，講演番号1P106, Sep. 2018.
36.	Shodai Kimura, Shigeki Kubo, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : Application and Development of Strontium-Mediated Alkylation of Amide Compounds, 日本化学会第98春季年会, 日本大学理工学部(千葉), 講演番号4H2-03, Mar. 2018.
37.	Kazuki Tani, Toshiki Hayashi, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : Development of One-Pot Sonogashira-Suzuki Tandem Coupling Reaction in Water, 日本化学会第98春季年会, 日本大学理工学部(千葉), 講演番号2PC-122, Mar. 2018.
38.	Mami Fujita, 宮崎泰彰, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : The Development of the New Synthetic Methods of Olefine Derivatives by Peterson Reaction Using Metallic Strontium, 日本化学会第98春季年会, 日本大学理工学部(千葉), 講演番号2PC-098, Mar. 2018.
39.	Yusuke Ishii, Sawa Tateda, Takahiro Nishizawa, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : Application of Strontium-Mediated Alkylation of Nitrogen-Containing Compounds, 日本化学会第98春季年会, 日本大学理工学部(千葉), 講演番号2PC-097, Mar. 2018.
40.	Ryo Kusaka, Satoshi D. Ohmura, Norikazu Miyoshi and Masaharu Ueno : Study of the unique coupling reactions using the concerted bismuth catalysis, 日本化学会第98春季年会, 日本大学理工学部(千葉), 講演番号2H2-08, Mar. 2018.
41.	Mami Fujita, 宮崎泰彰, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : 金属ストロンチウムを用いたアリルシランの新規合成法, 2017年日本化学会中国四国支部大会,鳥取産業体育館(鳥取),講演番号 OR54P, Nov. 2017.
42.	Kazuki Tani, Satoshi D. Ohmura, Norikazu Miyoshi and Masaharu Ueno : 薗頭-鈴木タンデムカップリング反応による水溶媒中でのワンポット多成分連結法の開発, 2017年日本化学会中国四国支部大会,鳥取産業体育館(鳥取),講演番号 OR44P, Nov. 2017.
43.	Shodai Kimura, Shigeki Kubo, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : Metallic Strontium-Mediated Monoalkylation of N,N-Dimethylamides, 64th Symposium on Organometallic Chemistry, Japan, Sep. 2017.
44.	Takahiro Nishizawa, Saki Kitakata, Sawa Tateda, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : Preparation of Metallacycle Intermediates Using Metallic Strontium and Its Application for New Reaction, 64th Symposium on Organometallic Chemistry, Japan, Sep. 2017.
45.	Ryosuke Shimoda, Yasuaki Miyazaki, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : Development of new synthetic method using strontium alkoxide, 28th Symposium on Physical Organic Chemistry, Sep. 2017.
46.	Satoshi D. Ohmura, Gen Nagaoka, Keisuke Yamana, Masaharu Ueno and Norikazu Miyoshi : Control of Luminescence Properties of Triarylamine Derivatives Based on Introduction of Alkyl Groups, 28th Symposium on Physical Organic Chemistry, Sep. 2017.
47.	Ryosuke Shimoda, 阿比留保奈美, 小松翔, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : ストロンチウムアルコキシドを用いる新規合成手法の開発, 日本化学会第97春季年会, 慶應義塾大学日吉キャンパス(神奈川),講演番号 4D4-02, Mar. 2017.
48.	Takahiro Nishizawa, 北方咲, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : 金属ストロンチウムを用いるメタラサイクル中間体の調製とそれを用いる新たな反応の開発, 日本化学会第97春季年会, 慶應義塾大学日吉キャンパス(神奈川),講演番号 4D4-01, Mar. 2017.
49.	Ryo Kusaka, Satoshi D. Ohmura, Norikazu Miyoshi and Masaharu Ueno : ビスマス塩を環境調和型触媒として用いるRitter反応の開発, 日本化学会第97春季年会, 慶應義塾大学日吉キャンパス(神奈川),講演番号 2E5-39, Mar. 2017.
50.	Masaharu Ueno, 喜多亜希子, 室井超帰, Satoshi D. Ohmura, Makoto Wada and Norikazu Miyoshi : ビスマス塩を触媒として用いた簡便かつ多様な酸化反応の開発, 日本化学会第97春季年会, 慶應義塾大学日吉キャンパス(神奈川),講演番号 2E5-38, Mar. 2017.
51.	Gen Nagaoka, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : 発光特性を有するトリアリールアミン誘導体の合成とストロンチウム試剤を用いた置換基効果の検討, 日本化学会第97春季年会, 慶應義塾大学日吉キャンパス(神奈川),講演番号 2PC-060, Mar. 2017.
52.	Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : 金属ストロンチウムを用いるアミド化合物の還元反応, 日本化学会第97春季年会, 慶應義塾大学日吉キャンパス(神奈川),講演番号 1PB-111, Mar. 2017.
53.	Shodai Kimura, 久保誠輝, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : 金属ストロンチウムを用いるアミド化合物のモノアルキル化反応, 日本化学会第97春季年会, 慶應義塾大学日吉キャンパス(神奈川),講演番号 1PB-110, Mar. 2017.
54.	Masaharu Ueno, 喜多亜希子, 室井超帰, Satoshi D. Ohmura, Makoto Wada and Norikazu Miyoshi : Development of the Aerobic Oxidation Reaction of Alcohols and Oxidative Esterification of Aldehydes Using Bismuth Salt as a Catalyst, The 49th Symposium on Chemical and Biological Oxidation, Nov. 2016.
55.	Ryo Kusaka, Satoshi D. Ohmura, Norikazu Miyoshi and Masaharu Ueno : ビスマス塩を触媒として用いるRitter反応の開発, 2016年日本化学会中国四国支部大会,香川大学(香川),講演番号 2P84, Nov. 2016.
56.	Takahiro NIshizawa, Saki Kitakata, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : 金属ストロンチウムを用いるメタラサイクル中間体の合成とそれを用いた反応の開発, 2016年日本化学会中国四国支部大会,香川大学(香川),講演番号 1J13, Nov. 2016.
57.	Sawa Tateda, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : ストロンチウムアミドを利用した合成手法の開発, 2016年日本化学会中国四国支部大会,香川大学(香川),講演番号 1J12, Nov. 2016.
58.	Keisuke Yamana, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : Synthesis and Electronic Properties of Triarylamine Derivatives Oriented to Functional Materials, 第27回基礎有機化学討論会, 広島国際会議場(広島), 講演番号 2P084, Sep. 2016.
59.	Satoshi D. Ohmura, Kenji Morita, Norikazu Miyoshi, Toshikazu Hirao and Toshiyuki Moriuchi : Chirality-induced Structure of Redox-active Phenylenediamine Derivatives through Introduction of Amino Acid Moieties, 第27回基礎有機化学討論会, 広島国際会議場(広島), 講演番号 2P067, Sep. 2016.
60.	Norikazu Miyoshi, Saki Kitakata, Sawa Tateda, Takahiro Nishizawa, Satoshi D. Ohmura and Masaharu Ueno : Study on Preparation and Reactivity of Sr-metallacycle Intermediates, 第27回基礎有機化学討論会, 広島国際会議場(広島), 講演番号 1C05, Sep. 2016.
61.	Masaharu Ueno, 喜多亜希子, 室井長帰, Satoshi D. Ohmura, Makoto Wada and Norikazu Miyoshi : Environmentally Benign Oxidation Reaction Using Bismuth Salt as a Catalyst, 日本化学会第96春季年会,同志社大学京田辺キャンパス(京都),講演番号 3H1-33, Mar. 2016.
62.	Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : Development of Sr-Mediated Hydrogenation of Aromatic Hydrocarbons, 日本化学会第96春季年会,同志社大学京田辺キャンパス(京都),講演番号 3H7-30, Mar. 2016.
63.	高橋春香, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : Convenient Synthesis of Esters Having Two Different Acetylene Groups Using Acetylene Carboxylic Acid and Metallic Strontium, 日本化学会第96春季年会,同志社大学京田辺キャンパス(京都),講演番号 3H7-29, Mar. 2016.
64.	立田彩和, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : Development of a new synthetic method using strontium amides, 日本化学会第96春季年会,同志社大学京田辺キャンパス(京都),講演番号 3PC-072, Mar. 2016.
65.	西澤高宏, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : Preparation of Metallacycle Intermediates Using Metallic Strontium and Its Application for Strontium Acetylide, 日本化学会第96春季年会,同志社大学京田辺キャンパス(京都),講演番号 3PC-071, Mar. 2016.
66.	Haruka TAKAHASHI, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : 金属ストロンチウムとアセチレンカルボン酸を用いる多置換イソベンゾフラノンの簡便合成手法の開発, 2015年日本化学会中国四国支部大会,岡山大学(岡山),講演番号 15EA04, Nov. 2015.
67.	Saki KITAKATA, Yasuaki MIYAZAKI, Hiroshi KUNI, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : 金属ストロンチウムを用いた新たなメタラサイクル中間体の合成と新規合成手法の開発, 2015年日本化学会中国四国支部大会,岡山大学(岡山),講演番号 15EA03, Nov. 2015.
68.	Toshiki HAYASHI, Satoshi D. Ohmura, Norikazu Miyoshi and Masaharu Ueno : ワンポットタンデム薗頭/鈴木-宮浦カップリング反応を用いたポリアリール化合物の効率的合成手法の開発, 2015年日本化学会中国四国支部大会,岡山大学(岡山),講演番号 14P59, Nov. 2015.
69.	Takahiro NISHIZAWA, Yasuaki MIYAZAKI, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : 金属ストロンチウムと共役ジエンを用いるメタラサイクルの調製とその応用, 2015年日本化学会中国四国支部大会,岡山大学(岡山),講演番号 14P57, Nov. 2015.
70.	Sawa TATEDA, Satoshi D. Ohmura, Masaharu Ueno and Norikazu Miyoshi : 有機ストロンチウムを塩基として用いる新規合成手法の開発, 2015年日本化学会中国四国支部大会,岡山大学(岡山),講演番号 14P55, Nov. 2015.
71.	Norikazu Miyoshi, Haruka TAKAHASHI, Satoshi D. Ohmura and Masaharu Ueno : 金属ストロンチウムとアセチレンカルボン酸エステルを用いる多置換イソベンゾフラノンの簡便合成法の開発, 第62回有機金属討論会,関西大学千里山キャンパス(大阪),講演番号 P3-01, Sep. 2015.
72.	Satoshi D. Ohmura, Toshiyuki MORIUCHI, Misato HIRANO, Norikazu Miyoshi and Toshikazu HIRAO : Luminescent Properties of Phenylenediamine Derivatives Based on Substituent Effect, Abstracts of Annual Meeting of Japan Chemical Society, Mar. 2015. (Keyword) Luminescence / pi-Conjugated Molecule / Hydrogen Bond
73.	Haruka TAKAHASHI, Sawa TATEDA, Yuka YAMAGUCHI, Yasuaki MIYAZAKI, Satoshi D. Ohmura and Norikazu Miyoshi : 金属ストロンチウムによるエステルのジアルキル化を用いるアセチレン骨格の簡便な合成法, Abstracts of Annual Meeting of Japan Chemical Society, Mar. 2015.
74.	Saki KITAKATA, Yuka YAKAGUCHI, Yasuaki MIYAZAKI, Satoshi D. Ohmura and Norikazu Miyoshi : Grignard試薬より効率のよい金属ストロンチウムを用いた嵩高いカルボニル化合物に対するアルキル化反応の開発, Abstracts of Annual Meeting of Japan Chemical Society, Mar. 2015.
75.	Shigeki KUBO, Saki KITAKATA, Satoshi D. Ohmura and Norikazu Miyoshi : Development of Sr-Mediated Monoalkylation of Amides, Abstracts of Annual Meeting of Japan Chemical Society, Mar. 2015. (Keyword) Metallic Strontium / Amides / Monoalkylation
76.	Ray S. Furuya, 齋藤隆仁, keiji Ido, Takayoshi Miyazaki, Kazuhiko Aiba, Norikazu Miyoshi, Hideo Araki, Daisuke Hinode, Katsuhiko Yoshimoto and Namie Sasaki : 徳島大学における「大学入門講座・読書レポート2014」の試み:読書からアカデミック・ライティングへ-, 平成26年度 FD推進プログラム大学教育カンファレンス in 徳島, Dec. 2014.
77.	Ray S. Furuya, Takahito Saito, keiji Ido, Takayoshi Miyazaki, Kazuhiko Aiba, Norikazu Miyoshi, Hideo Araki, Daisuke Hinode and Namie Sasaki : 徳島大学における「大学入門講座・読書レポート2014」の試み, 平成26年度全学FD 徳島大学教育カンファレンスin徳島, 14-15, Dec. 2014. (Keyword) 大学入門講座 / 読書レポート / 新入生 / 附属図書館
78.	Saki Kitakata, Hiroshi Kunii, Yasuaki Miyazaki, Satoshi D. Ohmura and Norikazu Miyoshi : 金属ストロンチウムを用いた新たなメタラサイクル中間体の生成と新規合成手法の開発, 2014ハロゲン利用ミニシンポジウム予稿集, Dec. 2014.
79.	Norikazu Miyoshi, Kitakata Saki, Kunii Hiroshi, Miyazaki Yasuaki and Satoshi D. Ohmura : 金属ストロンチウムとアゾ化合物を用いた新規反応活性種の創製とその応用, 第61回有機金属化学討論会予稿集, Sep. 2014.
80.	Shigeki Kubo, Yasuaki Miyazaki, Yuka Yamaguchi, Saki Kitakata, Satoshi D. Ohmura and Norikazu Miyoshi : The convenient synthesis of siliy ethers of bulky alcohols with bulky silyl chlorides using strontium, Abstracts of Annual Meeting of Japan Chemical Society, Mar. 2014. (Keyword) Metallic strontium / Silyl ethers / Silyl chlorides / Strontium alkoxides
81.	Yuka Yamaguchi, Yasuaki Miyazaki, Daisuke Kanehiro, Saki Kitakata, Shigeki Kubo, Satoshi D. Ohmura and Norikazu Miyoshi : Development and application of more effective Sr-mediated alkylation of carbonyl compounds compared with Grignard method, Abstracts of Annual Meeting of Japan Chemical Society, Mar. 2014. (Keyword) Metallic strontium / Berbier-type / Alkylation / carbonyl compound
82.	Saki Kitakata, Hiroshi Kunii, Yasuaki Miyazaki, Yuka Yamaguchi, Shigeki Kubo, Satoshi D. Ohmura and Norikazu Miyoshi : Development of new synthetic method by using metallic strontium and azo compounds -Alkylation of azo compounds and a formation of new reactive intermediates-, Abstracts of Annual Meeting of Japan Chemical Society, Mar. 2014. (Keyword) Metallic Strontium / Azobenzene / Alkylation
83.	Norikazu Miyoshi, Yasuaki Miyazaki, Yuka Yamaguchi, Saki Kitakata, Shigeki Kubo, Satoshi D. Ohmura and Makoto Wada : ストロンチウムアルコキシドと嵩高いシリルクロリドを用いる簡便なエーテル合成法の開発, 第66回有機合成化学協会関東支部シンポジウム予稿集, Nov. 2013.
84.	Yamaguchi Yuka, Yasuaki Miyazaki, Abiru Homami, Kanehiro Daisuke, Kitakata Saki, Kubo Shigeki, Makoto Wada and Norikazu Miyoshi : 金属ストロンチウムを用いたGrignard試薬を凌駕するエステルのジアルキル化反応の開発, 日本化学会中国四国支部大会講演要旨集, 142, Nov. 2013. (Keyword) Metallic strontium / ester / Diaklylation
85.	Shigeki Kubo, Yasuaki Miyazaki, Yuka Yamaguchi, Saki Kitakata, Satoshi D. Ohmura and Norikazu Miyoshi : ストロンチウムアルコキシドを用いるシリルエーテルの簡便合成手法の開発, 日本化学会中国四国支部大会講演要旨集, 238, Nov. 2013. (Keyword) Metallic strontium / Silyl ethers / Silyl chlorides
86.	Saki Kitakata, Yasuaki Miyazaki, Hiroshi Kunii, Yuka Yamaguchi, Shigeki Kubo, Satoshi D. Ohmura and Norikazu Miyoshi : 金属ストロンチウムとハロゲン化アルキルを用いるアゾ化合物のアルキル化反応, 日本化学会中国四国支部大会講演要旨集, 237, Nov. 2013. (Keyword) Metallic strontium / Azo compounds / Alkylation
87.	Norikazu Miyoshi, 宮崎泰彰, 山口祐佳, 北方咲, 久保誠輝, Makoto Kikuchi and Makoto Wada : ストロンチウムを用いる嵩高いアルコールと嵩高いシリルクロリドからの簡便なエーテル合成手法の開発, 第60回有機金属討論会, P1B-01, Sep. 2013.
88.	Norikazu Miyoshi : Development and Application for Unexpected Sr-mediated Reaction, 有機合成化学協会中国四国支部第69回パネル討論会 + Seminar on Green Sustainable Chemistry in Tottori(2013-1), Jun. 2013. (Keyword) strontium / organic synthesis
89.	山口祐佳, 宮崎泰彰, 阿比留保奈美, Makoto Kikuchi, Makoto Wada and Norikazu Miyoshi : Grignard試薬を凌駕する金属ストロンチウムを用いたエステルのジアルキル化反応の開発とその応用, Abstracts of Annual Meeting of Japan Chemical Society, Vol.93, 3F4-59, Mar. 2013.
90.	宮崎泰彰, 田嶋孝裕, 兼弘大介, 阿比留保奈美, Makoto Kikuchi, Makoto Wada and Norikazu Miyoshi : Srを用いるエステル化反応の開発とその応用, 2012年日本化学会西日本大会, Vol.2012, 2L07, Nov. 2012.
91.	Norikazu Miyoshi, 宮崎泰彰, 兼弘大介, 田嶋孝裕, Makoto Kikuchi and Makoto Wada : Development and Application for Unexpected Sr-mediated alkylation of Esters, 有機金属討論会, Vol.59, P2C-21, Sep. 2012.
92.	宮崎泰彰, 河井智加, Makoto Kikuchi, Makoto Wada and Norikazu Miyoshi : アルキルストロンチウムの還元性を利用したメタラサイクル中間体の生成とその応用, Abstracts of Annual Meeting of Japan Chemical Society, Vol.92, 4L2-05, Mar. 2012.
93.	Norikazu Miyoshi, 宮崎泰彰, 田嶋孝裕, 兼弘大介, Makoto Kikuchi and Makoto Wada : ストロンチウムを用いる嵩高い第3級アルコールエステルの簡便迅速合成法の開発, 第62回有機合成化学協会関東支部シンポジウム, C16, Nov. 2011.
94.	田嶋孝裕, 浅岡真司, Makoto Kikuchi, Makoto Wada and Norikazu Miyoshi : 嵩高い第3級アルコール由来のエステルの簡便合成法, 2011年日本化学会西日本大会, Vol.2011, 2H-10, Nov. 2011.
95.	宮崎泰彰, 福原早百合, 浅岡真司, Makoto Kikuchi, Makoto Wada and Norikazu Miyoshi : ストロンチウムを用いる嵩高い第三級エステルの簡便な合成法, 2011年日本化学会西日本大会, Vol.2011, 2H-09, Nov. 2011.
96.	Makoto Kikuchi, 岡田咲紀, Norikazu Miyoshi and Makoto Wada : 鉄-ケイ素複合酸化物を触媒とする炭化水素類の官能基化反応, 2011年日本化学会西日本大会, Vol.2011, 1H-03, Nov. 2011.
97.	Makoto Kikuchi, 井上岳, Norikazu Miyoshi and Makoto Wada : 無溶媒下で行う固体ブレンステッド酸を用いたRitter反応, 2011年日本化学会西日本大会, Vol.2011, 1H-03, Nov. 2011.
98.	兼弘大介, 湯浅綾, Makoto Kikuchi, Makoto Wada and Norikazu Miyoshi : Barbier型反応で進行するSrを用いたエステルへの嵩高いアルキル基の付加反応, 2011年日本化学会西日本大会, Vol.2011, 1H-02, Nov. 2011.
99.	宮崎泰彰, 河井智加, Makoto Kikuchi, Makoto Wada and Norikazu Miyoshi : アルキルストロンチウム種と二酸化炭素及びその等価体との反応の開発, Abstracts of Annual Meeting of Japan Chemical Society, Vol.91, 3PA-163, Mar. 2011.
100.	田嶋孝裕, 浅岡真司, Makoto Kikuchi, Makoto Wada and Norikazu Miyoshi : 嵩高い第3級アルコール由来のエステルの簡便合成とその応用, Abstracts of Annual Meeting of Japan Chemical Society, Vol.91, 3PA-162, Mar. 2011.
101.	兼弘大介, 湯浅綾, Makoto Kikuchi, Makoto Wada and Norikazu Miyoshi : Srを用いた簡便な代替えGrignard試薬の開発, Abstracts of Annual Meeting of Japan Chemical Society, Vol.91, 3PA-161, Mar. 2011.
102.	Norikazu Miyoshi, 兼弘大介, 田嶋孝裕, 宮崎泰彰, Makoto Kikuchi and Makoto Wada : 金属ストロンチウムを用いる簡便な代替Grignard 試薬の創製とその発展に関する検討, 第60回有機合成化学協会関東支部シンポジウム, B14, Dec. 2010.
103.	Norikazu Miyoshi, 兼弘大介, 田嶋孝裕, Makoto Kikuchi and Makoto Wada : 金属ストロンチウムを用いるハロゲン化アルキルとカルボン酸誘導体との反応, 2010年日本化学会西日本大会, Vol.2010, 1L-15, Nov. 2010.
104.	Takashi Yamamoto, Makoto Kikuchi, Saki Okada, 佐田知沙, Norikazu Miyoshi and 和田眞 : スチレン類二量化に有効な鉄―ケイ素複合酸化物触媒のXAFS解析, 第46回X線分析研究討論会, Oct. 2010.
105.	Norikazu Miyoshi : 高校の化学教育と大学における高大接続科目・基礎科目・教養科目との連携について, 2009年日本化学会西日本大会, Vol.2009, 1MO01, Mar. 2010.
106.	Norikazu Miyoshi, 松尾強, 森真理子, Makoto Kikuchi and Makoto Wada : 金属ストロンチウムを用いる安息香酸類へのp-アルキル化反応について, 2009年日本化学会西日本大会, Vol.2009, 2H21, Mar. 2010.
107.	田嶋孝裕, 浅岡真司, Makoto Kikuchi, Makoto Wada and Norikazu Miyoshi : 嵩高い第3級アルコール由来のエステル合成法の開発, Abstracts of Annual Meeting of Japan Chemical Society, Vol.90, 2PB-166, Mar. 2010.
108.	兼弘大介, 湯浅綾, Makoto Kikuchi, Makoto Wada and Norikazu Miyoshi : THP中で進行するストロンチウムを用いる簡便な第3級アルコール合成法の開発, Abstracts of Annual Meeting of Japan Chemical Society, Vol.90, 2PB-165, Mar. 2010.
109.	Makoto Kikuchi, 渡辺崇史, Norikazu Miyoshi and Makoto Wada : シリカゲル担持鉄触媒の調製とスチレン類の二量化反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.90, 2PB-170, Mar. 2010.
110.	Makoto Kikuchi, 井上岳, Norikazu Miyoshi and Makoto Wada : リン酸シリカゲルを触媒とするRitter反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.90, 2PB-044, Mar. 2010.
111.	Norikazu Miyoshi, 幸野正志, Makoto Wada, 松永星, 溝田巧 and 清水真 : 金属ストロンチウムを用いるイミン及びアルデヒドのピナコールカップリング, Abstracts of Annual Meeting of Japan Chemical Society, Vol.90, 3F7-51, Mar. 2010.
112.	Norikazu Miyoshi, Masashi Asaoka, Mariko Mori, Aya Yuasa and Makoto Wada : 金属ストロンチウムを用いるカルボン酸類へのBarbier型アルキル化反応の開発, 第54回有機合成化学協会関東支部シンポジウム, 114-115, Nov. 2007.
113.	Aya Yuasa, Shogo Takagi, Masashi Asaoka, Mariko Mori, Makoto Wada and Norikazu Miyoshi : 金属ストロンチウムを用いたエステルのBarbier型ジアルキル化反応の新展開, Abstracts of Annual Meeting of Japan Chemical Society, Vol.87, 2D7-06, Mar. 2007.
114.	Masashi Asaoka, Shogo Takagi, Aya Yuasa, Mariko Mori, Makoto Wada and Norikazu Miyoshi : 金属ストロンチウムを用いた三級エステル類の簡便な合成手法の開発, Abstracts of Annual Meeting of Japan Chemical Society, Vol.87, 2D7-05, Mar. 2007.
115.	Yasufumi Yunoki, Shouta Endo, Norikazu Miyoshi and Makoto Wada : リン酸シリカゲル上で進行するアルデヒドとアミンを用いる簡便なストレッカー合成法, Abstracts of Annual Meeting of Japan Chemical Society, Vol.87, 3C6-47, Mar. 2007.
116.	Hajime Sakata, Yuriko Kanoh, Chouki Muroi, Norikazu Miyoshi and Makoto Wada : リン酸シリカゲル上で進行するマイクロウェーブを用いたPET樹脂の分解, Abstracts of Annual Meeting of Japan Chemical Society, Vol.87, 4C5-28, Mar. 2007.
117.	Shouta Endo, Tomoe Yoshitake, Yoshimi Saiki, Norikazu Miyoshi and Makoto Wada : リン酸シリカゲル上で進行するエステルの分解反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.86, 3H4-17, Mar. 2006.
118.	Yuriko Kanoh, Yoshimi Saiki, Chouki Muroi, Masayuki Inoue, Norikazu Miyoshi and Makoto Wada : メタホウ酸上で進行するDehydroxylationを利用した還元的Friedel-Crafts反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.86, 1H5-10, Mar. 2006.
119.	Yuuka Hosokawa, Katsuhito Hamamatsu, Norihito Makita, Masayuki Inoue, Norikazu Miyoshi and Makoto Wada : 無溶媒シリカゲル上大気中にて進行するアルコールの酸化反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.86, 4J1-14, Mar. 2006.
120.	Masashi Asaoka, Aki Matsui, Tsuyoshi Matsuo, Makoto Wada and Norikazu Miyoshi : 金属ストロンチウムを用いるカルボン酸のBarbier型モノアルキル化反応の開発, Abstracts of Annual Meeting of Japan Chemical Society, Vol.86, 3H2-51, Mar. 2006.
121.	Mariko Mori, Daitetsu Ikehara, Tsuyoshi Matsuo, Makoto Wada and Norikazu Miyoshi : 金属ストロンチウムとヨウ化アルキルを用いた安息香酸および安息香酸誘導体のBarbier型1,6-付加反応の開発, Abstracts of Annual Meeting of Japan Chemical Society, Vol.86, 3H2-50, Mar. 2006.
122.	Aya Yuasa, Tsuyoshi Matsuo, Makoto Wada and Norikazu Miyoshi : 金属ストロンチウムを用いるエステルのBarbier型アルキル化反応の開発, Abstracts of Annual Meeting of Japan Chemical Society, Vol.86, 3H2-49, Mar. 2006.
123.	Norikazu Miyoshi : 金属ストロンチウムを用いるBarbier型合成手法の開発, 第21回若手化学者のための化学道場, 15-18, Sep. 2005.
124.	Tadashi Kouno, Daitetsu Ikehara, Tsuyoshi Matsuo, Makoto Wada and Norikazu Miyoshi : The Barbier-Type Alkylation of Imines Using Metallic Strontium and Alkyl Iodide, Abstracts of Annual Meeting of Japan Chemical Society, Vol.85, 3B3-06, Mar. 2005.
125.	Aki Matsui, Tsuyoshi Matsuo, Daitetsu Ikehara, Makoto Wada and Norikazu Miyoshi : The Barbier-Type Alkylation of Carboxylic Acids Using Metallic Strontium and Alkyl Iodide, Abstracts of Annual Meeting of Japan Chemical Society, Vol.85, 3B3-05, Mar. 2005.
126.	Tsuyoshi Matsuo, Daitetsu Ikehara, Tadashi Kouno, Makoto Wada and Norikazu Miyoshi : The Barbier-Type Alkylation of Esters Using Metallic Strontium and Alkyl Iodide, Abstracts of Annual Meeting of Japan Chemical Society, Vol.85, 3B3-04, Mar. 2005.
127.	Chouki Muroi, Jyunichi Yoshinari, Masayuki Inoue, Norikazu Miyoshi and Makoto Wada : Solvent-free Hetero Diels-Alder Reaction of Aldehydes with Non-Activated Dienes Mediated on B2O3-SiO2, Abstracts of Annual Meeting of Japan Chemical Society, Vol.85, 1B2-32, Mar. 2005.
128.	Katsuhito Hamamatsu, Yoshifumi Mitani, Masayuki Inoue, Norikazu Miyoshi and Makoto Wada : [4+2]Cycloaddition Reaction of N-Aryl Imines and Olefins Mediated on B2O3/SiO2, Abstracts of Annual Meeting of Japan Chemical Society, Vol.85, 1B2-33, Mar. 2005.
129.	Sandra Jacqueline Lock, Norikazu Miyoshi and Makoto Wada : Formation of Nitrogen-containing Hetercycle Compounds on a Rapidly-prepared Phosphoric Acid-Silica Gel Support, Abstracts of Annual Meeting of Japan Chemical Society, Vol.85, 1B2-32, Mar. 2005.
130.	Yoshimi Saiki, Kazuyo Sawa, Masayuki Inoue, Norikazu Miyoshi and Makoto Wada : A Mild and Novel Method for the Deprotection of Silyl Ethers on B2O3-SiO2, Abstracts of Annual Meeting of Japan Chemical Society, Vol.85, 1C2-48, Mar. 2005.
131.	Daitetsu Ikehara, Tsuyoshi Matsuo, Tadashi Kouno, Masafumi Oohira, Makoto Wada and Norikazu Miyoshi : 金属ストロンチウムとヨウ化アルキルを用いるイミンのBarbier型アルキル化反応の試み, Abstracts of Annual Meeting of Japan Chemical Society, Vol.84, 1B704, Mar. 2004.
132.	Kazuhiko Nakanishi, Norihito Makita, Norikazu Miyoshi and Makoto Wada : 臭化水素酸と過酸化水素を用いるアルコールの酸化反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.84, 2K332, Mar. 2004.
133.	Katsuhito Hamamatsu, Yoshifumi Mitani, Masayuki Inoue, Norikazu Miyoshi and Makoto Wada : 無溶媒かつホウ酸シリカゲル上にて進行するカルボニル-エン反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.84, 2K312, Mar. 2004.
134.	Jun^ichi Yoshinari, Yoshifumi Mitani, Masayuki Inoue, Norikazu Miyoshi and Makoto Wada : ホウ酸シリカゲルおよびメタホウ酸上で進行する無溶媒炭素-炭素結合生成反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.84, 2K311, Mar. 2004.
135.	Shin Iwata, Norikazu Miyoshi and Makoto Wada : フェニルボロン酸/シリカゲルを用いる無溶媒向山アルドール反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.84, 2K310, Mar. 2004.
136.	Kazuyo Sawa, Jun-ichi Yoshinari, Norikazu Miyoshi and Makoto Wada : 無溶媒かつメタホウ酸-シリカゲル上で進行するアルデヒドの還元反応及びα，β-不飽和ケトンの選択的1，4-還元反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.84, 2K308, Mar. 2004.
137.	Tomoe Yoshitake, Masayuki Inoue, Norikazu Miyoshi and Makoto Wada : ホウ酸シリカゲルと過酸化水素を用いる無溶媒Baeyer-Villiger酸化反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.84, 2K307, Mar. 2004.
138.	Megumi Iuchi, Toshihiro Sonoda, Norikazu Miyoshi and Makoto Wada : 二塩化ニッケルとn-Butyl Grignard試薬を用いる含水溶媒中でのアリルアルコールのケトンへの異性化反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.84, 1K335, Mar. 2004.
139.	Sandra Jacqueline Lock, Norikazu Miyoshi and Makoto Wada : 調製·再利用が容易なリン酸シリカゲル上にて進行するイミノアルドール反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.84, 3K211, Mar. 2004.
140.	Norikazu Miyoshi, Daitetsu Ikehara and Makoto Wada : 金属ストロンチウムを用いるアルキル化反応, 第46回有機合成化学協会関東支部シンポジウム, 97-98, Nov. 2003.
141.	Tomoe Yoshitake, Masayuki Inoue, Norikazu Miyoshi and Makoto Wada : 固体酸触媒と過酸化水素水を用いる新規酸化反応の開発, 第19回若手化学者のための化学道場2003, P-20, Sep. 2003.
142.	Yoshifumi Mitani, Masayuki Inoue, Katsuhito Hamamatsu, Norikazu Miyoshi and Makoto Wada : ホウ酸シリカゲル上にて進行する三成分連結型イミノアルドール反応およびカルボニルエン反応, 第19回若手化学者のための化学道場2003, P-16, Sep. 2003.
143.	Sandra Jacqueline Lock, Norikazu Miyoshi and Makoto Wada : 調製容易かつ再利用可能なリン酸シリカゲル上にて進行する無溶媒イミノアルドール反応, 第19回若手化学者のための化学道場2003, P-13, Sep. 2003.
144.	Kazuyo Sawa, Jun-ichi Yoshinari, Masayuki Inoue, Norikazu Miyoshi and Makoto Wada : 無溶媒かつホウ酸シリカゲルまたはメタホウ酸―シリカゲル上にて進行するアルデヒドの還元反応, 第19回若手化学者のための化学道場2003, P-12, Sep. 2003.
145.	Megumi Iuchi, Rika Kuwata, Norikazu Miyoshi and Makoto Wada : ビスマス化合物を用いる含水溶媒中，又は完全水中にて進行するカルボニル化合物及びニトロ化合物の還元反応, 第19回若手化学者のための化学道場2003, P-09, Sep. 2003.
146.	Mitsuko Matsuo, Kazuhiko Nakanishi, Tomoe Yoshitake, Norikazu Miyoshi and Makoto Wada : 三塩化ビスマスと過酸化水素を用いるケトンのα-塩素化反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.83, 3J111, Mar. 2003.
147.	Norihito Makita, Shinji Maeda, Mitsuko Matsuo, Norikazu Miyoshi and Makoto Wada : 三塩化ビスマスと過酸化水素を用いるα―ヒドロキシケトンの酸化開裂反応およびアジピン酸の合成, Abstracts of Annual Meeting of Japan Chemical Society, Vol.83, 3J110, Mar. 2003.
148.	Kazuyo Sawa, Chiharu Kitajima, Sawako Uehara, Masayuki Inoue, Norikazu Miyoshi and Makoto Wada : ホウ酸シリカゲル上にて進行するアルデヒドの還元反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.83, 3H646, Mar. 2003.
149.	Yoshifumi MItani, Masayuki Inoue, Jun-ichi Yoshinari, Norikazu Miyoshi and Makoto Wada : ホウ酸シリカゲル上にて進行する三成分連結型イミノアルドール反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.83, 3H645, Mar. 2003.
150.	Toshihiro Sonoda, Ai Hinamoto, Jones Wilm, Megumi Iuchi, Norikazu Miyoshi and Makoto Wada : 二塩化ニッケルとn-ブチルリチウムを用いる含水溶媒中でのCannizzaro反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.83, 1H437, Mar. 2003.
151.	Sandra Jacqueline Lock, Keith Smith, Norikazu Miyoshi and Makoto Wada : フッ化物イオンを含んだ水あるいは0.5M塩酸溶媒中，ビスマスと臭化アリルを用いるホモアリリックアルコールのone-pot合成反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.83, 4G602, Mar. 2003.
152.	Daitetsu Ikehara, Koji Kamiura, Makoto Wada and Norikazu Miyoshi : ストロンチウムを用いる合成手法の開発, 日本化学会西日本大会講演予稿集, Vol.2002, 2C24, Nov. 2002.
153.	Akiko Kita, Mitsuko Matsuo, Norihito Makita, Norikazu Miyoshi and Makoto Wada : 三塩化ビスマスと過酸化水素を用いる環境調和適応型新規酸化反応の開発, 第35回酸化反応討論会, O-05, Nov. 2002.
154.	Yoshifumi Mitani, Norikazu Miyoshi and Makoto Wada : シリカゲルまたはホウ酸シリカゲル上にて進行するアルドール反応およびイミノアルドール反応, 第18回若手化学者のための化学道場2002, P-33, Jul. 2002.
155.	Norihito Makita, Norikazu Miyoshi and Makoto Wada : 三塩化ビスマスと過酸化水素を用いる新規酸化反応の開発, 第18回若手化学者のための化学道場2002, P-33, Jul. 2002.
156.	Toshihiro Sonoda, Norikazu Miyoshi and Makoto Wada : 二塩化ニッケルとベンジルGrignard試薬を用いる含水溶媒中でのアルデヒドの還元反応および末端オレフィンの異性化反応, 第18回若手化学者のための化学道場2002, P-21, Jul. 2002.
157.	Toshihiro Sonoda, Rika Kuwata, Yuya Sueki, Norikazu Miyoshi and Makoto Wada : 二塩化ニッケルとベンジルGrignard試薬を用いる含水溶媒中でのアルデヒドの還元反応及び末端オレフィンの異性化反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.81, 3G8-14, Mar. 2002.
158.	Yoshifui Mitani, Rika Kuwata, Atsushi Shio, Norikazu Miyoshi and Makoto Wada : 三塩化ビスマスとアルミニウムを用いる水中で進行するカルボニル化合物の還元反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.81, 3G8-13, Mar. 2002.
159.	Sawako Uehara, Keigo Murabe, Shoujirou Ikebuchi, Seiki Minami, Norikazu Miyoshi and Makoto Wada : 三塩化ビスマスを触媒とした過酸化水素を用いるBaeyer-Villiger酸化, Abstracts of Annual Meeting of Japan Chemical Society, Vol.81, 3G8-10, Mar. 2002.
160.	Mitsuko Matsuo, Akiko Kita, Norihito Makita, Makoto Maeda, Norikazu Miyoshi and Makoto Wada : 三塩化ビスマスと過酸化水素を用いるアルデヒドの酸化的エステル化反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.81, 3G809, Mar. 2002.
161.	Chiharu Kitajima, Yoshifumi Mitani, Hirotaka Shindo, Norikazu Miyoshi and Makoto Wada : シリカゲル上で進行するアルドール反応およびイミノアルドール反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.81, 2G9-09, Mar. 2002.
162.	Norikazu Miyoshi : ストロンチウム金属の還元性を利用した合成反応の開発, 第17回若手化学者のための化学道場2001, Jul. 2001.
163.	Norikazu Miyoshi and Makoto Wada : 三塩化ビスマスと過酸化水素を用いる新規酸化反応の開発, 第17回若手化学者のための化学道場2001, P-22, Jul. 2001.
164.	Rika Kuwata, Norikazu Miyoshi and Makoto Wada : 三塩化ビスマスとアルミニウムを用いる含水溶媒中での還元反応, 第17回若手化学者のための化学道場2001, P-21, Jul. 2001.
165.	Chiharu Kitajima, Norikazu Miyoshi and Makoto Wada : シリカゲル上で進行するアルデヒド，アミンを用いるイミンへの求核的付加反応, 第17回若手化学者のための化学道場2001, P-20, Jul. 2001.
166.	Norikazu Miyoshi, Koji Kamiura, Mika Sone, Junko Hosokawa, Akiko Kita and Rika Kuwata : Organic Synthesis Using Strontium Metal, Abstracts of Annual Meeting of Japan Chemical Society, Vol.78, 3F4-31, Mar. 2000.
167.	Koji Kamiura, Shunsuke Murakami, Norikazu Miyoshi and Makoto Wada : メタノールまたは含水溶媒中で進行するトリブチルスズヒドリドを用いるアルデヒドの還元反応, Abstracts of Annual Meeting of Japan Chemical Society, Vol.76, No.2B6, 32, Mar. 1999.
168.	Tomohiro Fukuma, Sonoe Nagayama, Akifumi Tsuchiura, Norikazu Miyoshi and Makoto Wada : ビスマス化合物を用いる新しい有機合成反応の開発, ヘテロ原子化学討論会講演予稿集, Vol.25, 53, Dec. 1998.

Et cetera, Workshop:

1.	Norikazu Miyoshi : 金属Srを用いるGrignard試薬を凌駕する?した?ちょっと変わった反応の開発とその応用, 日本プロセス化学会東四国地区フォーラム, Jan. 2014. (Keyword) strontium / organic synthesis
2.	Norikazu Miyoshi : 新しい反応試剤の開発, 中国四国支部化学懇談会, Dec. 2001.
3.	Makoto Wada and Norikazu Miyoshi : 環境調和適応型有機合成反応-水中での有機合成反応を中心にして-, 日本化学会中国四国支部第32回化学懇談会, Apr. 2000.

Report:

1.	Takanori Satoh, Masanori Miyata, Kazuhiro Tsutsumi, Steve Toshihisa Fukuda, Takahito Saito, Ray S. Furuya, Katsuhiko Yoshimoto, Norikazu Miyoshi and Hideo Araki : 全学共通教育センター FDの歴史, 徳島大学FDの歴史, Vol.2, 91-111, Tokushima, Dec. 2014.

Patent:

1.	Norikazu Miyoshi, Tsuyoshi Matsuo, Aya Yuasa and Ikuko Mitani : 第3級アルコールの製造方法, 2009-199807, .
2.	Norikazu Miyoshi, Makoto Kikuchi and 田嶋孝裕 : 第3級アルコール由来のエステルの製造方法, 2011-052693 (Mar. 2011), .
3.	Makoto Wada and Norikazu Miyoshi : ポリエステルの分解方法および芳香族ジカルボン酸の回収方法, 2006-03415 (Feb. 2006), .
4.	Norikazu Miyoshi, Tsuyoshi Matsuo and Makoto Wada : 第3級アルコールの製造方法, 2005-174781 (Jun. 2005), 4825969 (Sep. 2011).

Grants-in-Aid for Scientific Research (KAKEN Grants Database @ NII.ac.jp)

Synthesis of new intermediate by reductive umpolung reaction using metallic strontium (Project/Area Number: 24550056 )
多機能反応剤の開発-有機ストロンチウムの調製と反応- (Project/Area Number: 19020049 )
Green Chemistry - Development of Environment Benain Oxidation (Project/Area Number: 13640536 )
Development of Grignard-Type Addition Reaction and Application of Its into the Practical Synthetic Process (Project/Area Number: 11554024 )
Development of Synthetic Reactions and Effect Chemicals (Project/Area Number: 10045029 )
ビスマス化合物を用いる水存在下でも進行する簡便なGrignard型反応の開発 (Project/Area Number: 09740474 )
LATTICE-CONTROLLED SOLID STATE-SPECIFIC AND ENANTIOSELECTIVE REACTIONS (Project/Area Number: 04640516 )
Search by Researcher Number (40219829)

Professor : Miyoshi, Norikazu

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Grants-in-Aid for Scientific Research (KAKEN Grants Database @ NII.ac.jp)